1-Propene, 1,3,3,3-tetrafluoro-, (1Z)-

Base Information

• Chemical Name: 1-Propene, 1,3,3,3-tetrafluoro-, (1Z)-
• CAS No.: 29118-25-0
• Deprecated CAS: 1656992-21-0
• Molecular Formula: C3H2F4
• Molecular Weight: 114.042
• European Community (EC) Number: 826-544-6
• UNII: XXV68QSS1E
• DSSTox Substance ID: DTXSID70885447
• Nikkaji Number: J1.972.725D
• Wikidata: Q27294046

Synonyms:29118-25-0;1-Propene, 1,3,3,3-tetrafluoro-, (1Z)-;cis-HFO 1234ZE;(Z)-1,3,3,3-tetrafluoropropene;Z-HFC 1234ZE;Z-1,3,3,3-Tetrafluoropropene;cis-1,3,3,3-Tetrafluoropropene;UNII-XXV68QSS1E;XXV68QSS1E;cis-1,1,1,3-Tetrafluoro-2-propene;1,3,3,3-Tetrafluoropropene, (1Z)-;Propene, 1,3,3,3-tetrafluoro-, (Z)-;(Z)-1,3,3,3-tetrafluoroprop-1-ene;1-Propene, 1,3,3,3-tetrafluoro-, (Z)-;cis-1,3,3,3-tetrafluoroprop-1-ene;(1Z)-1,3,3,3-Tetrafluoroprop-1-ene;SCHEMBL25830;HFO-1234ze(Z);C3H2F4;R-1234ze(Z);DTXSID70885447;CDOOAUSHHFGWSA-UPHRSURJSA-N;(1Z)-1,3,3,3-tetrafluoropropene;MFCD18071081;(Z)-1,3,3,3-Tetrafluoro-1-propene;Q27294046

Chemical Property of 1-Propene, 1,3,3,3-tetrafluoro-, (1Z)-

Chemical Property:

• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 114.00926271
• Heavy Atom Count: 7
• Complexity: 69.5

Purity/Quality:

99% min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=CF)C(F)(F)F
• Isomeric SMILES: C(=C\F)\C(F)(F)F

Technology Process of 1-Propene, 1,3,3,3-tetrafluoro-, (1Z)-

There total 45 articles about 1-Propene, 1,3,3,3-tetrafluoro-, (1Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.6%

trans-1-chloro-3,3,3-trifluoropropene (102687-65-0) → 1,1,1,3,3-Pentafluoropropane (460-73-1) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With aluminum oxide; chromium(III) chloride hexahydrate; hydrogen fluoride; at 360 - 450 ℃; for 1h; under 750.075 - 1500.15 Torr; Inert atmosphere;

Reference yield: 29.0%

perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → 1,2,3,3,3-pentafluoroprop-1-ene (2252-83-7,5528-43-8,5595-10-8) + trans-1,3,3,3-tetrafluoropropene (29118-24-9) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With dimethylsulfide borane complex; In benzene-d6; at 100 ℃; for 96h; Time;

Reference yield:

trans-1,3,3,3-tetrafluoropropene (29118-24-9) → 1,1,1,3,3,3-hexafluoropropane (690-39-1) + 2,3,3,3-tetrafluoro-propene (754-12-1) + 1,1,1,3,3-Pentafluoropropane (460-73-1) + (Z)-1,3,3,3-tetrafluoropropene (29118-25-0)

Guidance literature:

With hydrogen fluoride; chromium(III) oxide; at 350 ℃; Product distribution / selectivity;

upstream raw materials:

1,1,1,3-tetrafluoro-3-iodo-propane

1,1,1,2,3-pentafluoropropane

trans-1,3,3,3-tetrafluoropropene

trans-1-chloro-3,3,3-trifluoropropene

Downstream raw materials:

trans-1,3,3,3-tetrafluoropropene

1,1,1,3,3-Pentafluoropropane

(Z)-1-chloro-3,3,3-trifluoro-1-propene

trans-1-chloro-3,3,3-trifluoropropene

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