2,4,5,7-TETRANITRO-9H-FLUORENE

Base Information

• Chemical Name: 2,4,5,7-TETRANITRO-9H-FLUORENE
• CAS No.: 29210-71-7
• Molecular Formula: C13H6N4O8
• Molecular Weight: 346.213
• Mol file: 29210-71-7.mol

Synonyms:2,4,5,7-Tetranitro-fluoren-9-on;2,4,5,7-Tetranitro-9H-fluoren-9-one;Fluoren-9-one,2,4,5,7-tetranitro;9H-Fluoren-9-one,tetranitro;9H-Fluoren-9-one,2,4,5,7-tetranitro;2,4,5,7-tetra-nitrofluorene;2,4,5,7-tetranitro-fluoren-9-one;Tetranitrofluorenone;2,4,7-trinitrofluorene;2,4,5,7-Tetranitro-9-fluorenone;2,4,5,7-Tetranitrofluorenone;

Chemical Property of 2,4,5,7-TETRANITRO-9H-FLUORENE

Chemical Property:

• Melting Point: 298-300 °C(Solv: acetic acid (64-19-7))
• Boiling Point: 551.1±50.0 °C(Predicted)
• PSA: 183.28000
• Density: 1.769±0.06 g/cm3(Predicted)
• LogP: 4.98340

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,4,5,7-TETRANITRO-9H-FLUORENE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4,5,7-TETRANITRO-9H-FLUORENE

There total 2 articles about 2,4,5,7-TETRANITRO-9H-FLUORENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.5%

9H-fluorene (86-73-7) → 2,4,5,7-tetranitro-9H-fluorene (29210-71-7)

Guidance literature:

With sulfuric acid; nitric acid; at 102 - 105 ℃; for 1h;

Reference yield:

9-fluorenone (486-25-9,952573-42-1) → 2,4,5,7-tetranitro-9H-fluorene (29210-71-7)

Guidance literature:

With sulfuric acid; nitric acid; at 60 ℃; for 1.5h;

DOI:10.1039/d0cc01236j

Reference yield: 98.0%

4-[N,N-bis(n-propyl)amino]benzaldehyde (613-28-5) + 2,4,5,7-tetranitro-9H-fluorene (29210-71-7) → 9--2,4,5,7-tetranitrofluorene

Guidance literature:

With acetic anhydride; at 50 ℃; for 1.5h;

upstream raw materials:

9H-fluorene

9-fluorenone

Downstream raw materials:

9-<3-(N-methyl-N-phenylamino)-2-propenylidene>-2,4,5,7-tetranitrofluorene

9-(N,N-diphenylaminomethylene)-2,4,5,7-tetranitrofluorene

9-(3,5-dichloro-2-methoxyphenylmethylene)-2,4,5,7-tetranitrofluorene

Refernces

• 1、 Dem'yanov, P.I.,Fedorova, G.V.,Petrosyan, V.S.,Reutov, O.A.. "PREPARATION OF 2,4,5,7-TETRANITROFLUORENE AND 9-ARYLIDENE-2,4,5,7-TETRANITROFLUORENES". . p. 2196. Retrieved 1984.
• 2、 Semenenko, N. M.,Abramov, V. N.,Kravchenko, N. V.,Trushina, V. S.,Buyanovskaya, P. G.,et al.. "SYNTHESIS AND INVESTIGATION OF THE ELECTRON-ACCEPTOR PROPERTIES OF 9-(ARYLMETHYLENE)-2,4,5,7-TETRANITROFLUORENES". . p. 284 - 290. Retrieved 2007/10/02.