Cyclohexanecarboxaldehyde, 1-(2-propen-1-yl)-

Base Information

• Chemical Name: Cyclohexanecarboxaldehyde, 1-(2-propen-1-yl)-
• CAS No.: 29517-58-6
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol file: 29517-58-6.mol

Synonyms:1-Allyl-cyclohexancarbaldehyd;CYCLOHEXANECARBOXALDEHYDE,1-(2-PROPEN-1-YL)-;1-allyl-cyclohexanecarbaldehyde;1-allyl-1-formylcyclohexane;1-allyl-cyclohexanecarboxaldehyde;

Chemical Property of Cyclohexanecarboxaldehyde, 1-(2-propen-1-yl)-

Chemical Property:

• Boiling Point: 105-107 °C(Press: 32 Torr)
• PSA: 17.07000
• Density: 0.947±0.06 g/cm3(Predicted)
• LogP: 2.71190

Purity/Quality:

98%min ^*data from raw suppliers

1-Allylcyclohexanecarbaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclohexanecarboxaldehyde, 1-(2-propen-1-yl)-

There total 32 articles about Cyclohexanecarboxaldehyde, 1-(2-propen-1-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

Allyl cyclohexylidenemethyl carbonate (86950-88-1) → 1-cyclohexene-1-carboxaldehyde (1192-88-7) + 1-allylcyclohexanecarbaldehyde (29517-58-6) + cyclohexanecarbaldehyde (2043-61-0)

Guidance literature:

palladium diacetate; triphenylphosphine; In acetonitrile; for 1.5h; Yields of byproduct given; Heating;

DOI:10.1055/s-1987-28145

Reference yield: 82.0%

allyl alcohol (107-18-6) + cyclohexanecarbaldehyde (2043-61-0) → 1-allylcyclohexanecarbaldehyde (29517-58-6)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In methanol; at 80 ℃; for 16h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;

DOI:10.1039/d0cc02263b

Reference yield: 80.0%

[1-(1-Allyl-cyclohexyl)-meth-(E)-ylidene]-tert-butyl-amine → 1-allylcyclohexanecarbaldehyde (29517-58-6)

Guidance literature:

With oxalic acid; In dichloromethane; water; for 2h; Heating;

DOI:10.1016/S0040-4020(97)00688-1

upstream raw materials:

allyl alcohol

cyclohexanecarbaldehyde

1-Pyrrolidinyl-methan-phosphonsaeure-diethylester

cyclohexanone

Downstream raw materials:

1-allylcyclohexyl ethyl ketone

1-(1'-hydroxy-4'-methoxy-2'-butynyl)-1-(3'-propenyl)cyclohexane

1-allylcyclohexane-1-nitrile

((1-allylcyclohexyl)ethynyl)benzene

Refernces

• 1、 Carbó, Jorge J.,Fernández, Elena,Maza, Ricardo J.,Royes, Jordi. "Consecutive borylcupration/C-C coupling of ?-alkenyl aldehydes towards diastereoselective 2-(borylmethyl)cycloalkanols". supporting information. p. 5973 - 5976. Retrieved 2020/06/05.
• 2、 Bernhard, Yann,Thomson, Brodie,Ferey, Vincent,Sauthier, Mathieu. "Nickel-Catalyzed α-Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols". supporting information. p. 7460 - 7464. Retrieved 2017/06/13.