Lithium thioethoxide

Base Information

• Chemical Name: Lithium thioethoxide
• CAS No.: 30383-01-8
• Molecular Formula: C2H6S.Li
• Molecular Weight: 68.0687
• Hs Code.: 2930909090
• European Community (EC) Number: 689-523-9
• DSSTox Substance ID: DTXSID00446287
• Mol file: 30383-01-8.mol

Synonyms:Lithium thioethoxide;30383-01-8;lithium;ethanethiolate;liset;Lithium Ethanethiolate;Lithium thioethoxide, 80%;DTXSID00446287;JPSNJFMTQIIVFG-UHFFFAOYSA-M;AKOS025295089

Chemical Property of Lithium thioethoxide

Chemical Property:

• Melting Point: 316-333°C
• PSA: 0.00000
• LogP: 0.55320
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 68.02719977
• Heavy Atom Count: 4
• Complexity: 6

Purity/Quality:

99% ^*data from raw suppliers

Lithium thioethoxide 80% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 11-14-34
• Safety Statements: 16-26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].CC[S-]
• Uses: Reactant for preparation of:Microwave-assisted cleavage of aryl methyl ethersTriply thiolate-bridged diiron complexes(+)-batzelladine A and (-)-batzelladine D

Technology Process of Lithium thioethoxide

There total 2 articles about Lithium thioethoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethanethiol (75-08-1) → lithium thioethoxide (30383-01-8)

Guidance literature:

With n-butyllithium; In hexane; at -60 ℃;

DOI:10.3987/COM-96-7477

Reference yield:

→ lithium thioethoxide (30383-01-8)

Guidance literature:

Reference yield: 96.0%

(+/-)-(3SR,4SR)-1,1,1-trichloro-4-[N-(diphenylphosphinoyl)amino]-3-methyl-4-phenylbutan-2-one + lithium thioethoxide (30383-01-8) + ethanethiol (75-08-1) → (+/-)-(3SR,4SR)-4-[N-(diphenylphosphinoyl)amino]-1,1-bis(ethylsulfanyl)-3-methyl-4-phenylbutan-2-one

Guidance literature:

In tetrahydrofuran; hexane; at 20 ℃; for 0.25h;

DOI:10.1002/anie.200600227

upstream raw materials:

ethanethiol

Downstream raw materials:

2-methyl-2-heptene

1-(ethylthio)-2-methylpropene

(E)-2-ethylthio-1-nitroethylene

(E)-<2-(Ethylthio)ethenylphenyl>sulfon