Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

Base Information

Chemical Name:Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2
CAS No.:869588-47-6
Molecular Formula:C₂₈H₂₉Br₂O₁₀PRh₂
Molecular Weight:922.125
Hs Code.:

Rh<sub>2</sub>(O<sub>2</sub>CCH<sub>3</sub>)3((BrC<sub>6</sub>H<sub>3</sub>)P(BrC<sub>6</sub>H<sub>4</sub>)(C<sub>6</sub>H<sub>5</sub>))(CH<sub>3</sub>COOH)2

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Suppliers and Price of Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

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Chemical Property of Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

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Technology Process of Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

There total 1 articles about Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: tetra[μ-acetato-bis(methanol)]dirhodium

: 84591-80-0
bis(4-bromophenyl)(phenyl)phosphine

: 64-19-7,77671-22-8
acetic acid

: 869588-47-6
Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

: 869588-51-2
Rh₂(O₂CCH₃)3((C₆H₄)P(BrC₆H₄)2)(CH₃COOH)2

Guidance literature:: In acetic acid; toluene; under Ar; Rh complex dissolved under reflux in toluene-acetic acid; phosphine (1.1 equiv.) in toluene added slowly; stirred without heating for 0.5 h; refluxed for 4 h; evapd. to dryness; column chromd. (silica gel, hexane-EtOAc-acetic acid); deep blue band sepd.; solvent removed; recrystd. from CH2Cl2-hexane; mixt. of monometallated complexes obtained; elem. anal.;
DOI:10.1016/j.jorganchem.2004.10.062

Reference yield: 37.0%

: 869588-47-6
Rh₂(O₂CCH₃)3((BrC₆H₃)P(BrC₆H₄)(C₆H₅))(CH₃COOH)2

: 603-35-0
triphenylphosphine

: Rh₂(O₂CCH₃)2((BrC₆H₃)P(BrC₆H₄)(C₆H₅))((C₆H₄)P(C₆H₅)2)(CH₃COOH)2

: Rh₂(O₂CCH₃)2((C₆H₄)P(BrC₆H₄)2)((C₆H₄)P(C₆H₅)2)(CH₃COOH)2

: Rh₂(O₂CCH₃)2((BrC₆H₃)P(BrC₆H₄)(C₆H₅))((C₆H₄)P(C₆H₅)2)(CH₃COOH)2

Guidance literature:: In acetic acid; toluene; Irradiation (UV/VIS); under Ar; Rh complex and PPh3 (molar ratio 1:1.1) dissolved in toluene-acetic acid; stirred and irradiated for 20 h; solvent removed under reduced pressure; dissolved in CH2Cl2-hexane; sepd. by column chromy. (silica gel, hexane-EtOAc-acetic acid); two red bands collected; evapd. to dryness; recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2004.10.062