(R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol

Base Information

Chemical Name:(R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol
CAS No.:30689-78-2
Molecular Formula:C17H34O
Molecular Weight:254.456
Hs Code.:
DSSTox Substance ID:DTXSID301017027
Nikkaji Number:J596.608F
Mol file:30689-78-2.mol

Synonyms:(R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol;30689-78-2;SCHEMBL7702597;QRFJDYPDABYWFH-XTKXOIQPSA-N;DTXSID301017027;(8Z)-14-Methyl-8-hexadecen-1-ol #

Suppliers and Price of (R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of (R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol

Chemical Property:

Boiling Point:341.7±11.0 °C(Predicted)
PSA：20.23000
Density:0.846±0.06 g/cm3(Predicted)
LogP:5.48200
XLogP3:6.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:13
Exact Mass:254.260965704
Heavy Atom Count:18
Complexity:174

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(C)CCCCC=CCCCCCCCO
Isomeric SMILES:CC[C@@H](C)CCCC/C=C\CCCCCCCO

Technology Process of (R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol

There total 2 articles about (R)-(-)-(Z)-14-Methyl-8-hexadecen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 821-57-8
7-chloroheptanoic acid

: 30689-78-2
(Z)-14-Methyl-8-Hexadecen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / tetrahydrofuran; hexamethylphosphoric acid triamide / 1) 20 deg C, 12 h, 2) 40 deg C, 5 h

2: 81 percent / LiAlH₄ / diethyl ether / 1 h / Heating

3: 62 percent / 1) LiNH₂ / 1) liq. NH₃ - THF, -40 deg C, 2) THF - HMPT, 40 deg C, 3 h

4: 90 percent / H₂ / 5percent Pd/BaSO₄ - quinoline / methanol / Ambient temperature

With lithium aluminium tetrahydride; lithium amide; hydrogen; quinoline; Pd-BaSO₄; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether;

Reference yield:

: 10422-35-2,99032-67-4,534-00-9,5973-11-5
1-bromo-2-methyl-butane

: 30689-78-2
(Z)-14-Methyl-8-Hexadecen-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) Mg / 1.) ether, 2.) ether, reflux, 16 h

2: 1.) NaBH₄, BF₃-etherate, 2.) 3 N aq. NaOH, 3.) 30percent aq. H₂O₂ / 1.) THF, 20-25 deg C, 20-25 min, 3.) THF, 30-35 deg C, 2 h

3: 76 percent / phosphorus tribromide / 20 h / 55 - 60 °C

4: 66 percent / liquid ammonia / 6 h

5: 1.) lithium amide, hexamethylphosphorotriamide / 1.) 20 deg C, 1 h, 2.) 40-45 deg C, 10 h

6: sodium borohydride, ethylenediamine / nickel acetate / aq. ethanol

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; sodium tetrahydroborate; lithium amide; boron trifluoride diethyl etherate; dihydrogen peroxide; phosphorus tribromide; magnesium; ethylenediamine; nickel diacetate; In ethanol; ammonia;

Reference yield: 79.0%

: 30689-78-2
(Z)-14-Methyl-8-Hexadecen-1-ol

: 60609-53-2,60609-52-1
(Z)-14-Methyl-8-Hexadecenal

Guidance literature:: With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; In dichloromethane; at 0 - 20 ℃; for 2.5h; Reagent/catalyst; Temperature;