4,4'-Bis(phenyloxalyl)benzophenone

Base Information

Chemical Name:4,4'-Bis(phenyloxalyl)benzophenone
CAS No.:31224-78-9
Molecular Formula:C29H18O5
Molecular Weight:446.459
Hs Code.:
DSSTox Substance ID:DTXSID401204578
Nikkaji Number:J954.244B
Mol file:31224-78-9.mol

Synonyms:SCHEMBL11312011;DTXSID401204578;4,4'-Bis(phenyloxalyl)benzophenone;4,4'-bis(phenylglyoxalyl)benzophenone;1,1'-(Carbonyldi-4,1-phenylene)bis[2-phenylethanedione];31224-78-9

Suppliers and Price of 4,4'-Bis(phenyloxalyl)benzophenone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4,4'-Bis(phenyloxalyl)benzophenone

Chemical Property:

XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:446.11542367
Heavy Atom Count:34
Complexity:706

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)C(=O)C(=O)C2=CC=C(C=C2)C(=O)C3=CC=C(C=C3)C(=O)C(=O)C4=CC=CC=C4

Technology Process of 4,4'-Bis(phenyloxalyl)benzophenone

There total 3 articles about 4,4'-Bis(phenyloxalyl)benzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 49674-70-6
4,4'-bis(phenylethynyl)benzophenone

: 31224-78-9
4,4'-bis(phenylglyoxalyl)diphenylketone

Guidance literature:: With iodine; dimethyl sulfoxide; at 155 ℃; for 22h;
DOI:10.1007/BF01435794

Reference yield:

: 5630-56-8
4,4'-diiodobenzophenone

: 31224-78-9
4,4'-bis(phenylglyoxalyl)diphenylketone

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / PdCl₂(Ph₃P)2, Ph₃P, CuI, Et₃N / dimethylformamide / 8 h / 90 °C

2: 93 percent / I₂, DMSO / 22 h / 155 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iodine; dimethyl sulfoxide; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1007/BF01435794

Reference yield:

: 536-74-3
phenylacetylene

: 31224-78-9
4,4'-bis(phenylglyoxalyl)diphenylketone

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / PdCl₂(Ph₃P)2, Ph₃P, CuI, Et₃N / dimethylformamide / 8 h / 90 °C

2: 93 percent / I₂, DMSO / 22 h / 155 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iodine; dimethyl sulfoxide; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1007/BF01435794