5630-56-8

Usage

Uses

Used in Organic Synthesis:
Bis(4-iodophenyl)methanone is utilized as a reagent for its propensity to engage in nucleophilic substitution reactions, which is instrumental in the preparation of a diverse array of organic compounds.
Used in Pharmaceutical Production:
bis(4-iodophenyl)methanone plays a significant role in the manufacturing process of pharmaceuticals, contributing to the development of various medications due to its reactive nature and ability to form key intermediates in drug synthesis.
Used in Agrochemical Production:
Bis(4-iodophenyl)methanone is also employed in the production of agrochemicals, where its reactivity is harnessed to create essential components for agricultural applications, such as pesticides and fertilizers.
Used in Industrial Chemical Production:
Its application extends to the broader scope of industrial chemical production, where bis(4-iodophenyl)methanone is used to synthesize a range of chemicals that are vital for different industries.
Safety Note:
Due to its toxic nature, bis(4-iodophenyl)methanone should be handled with caution. It is crucial to work in a well-ventilated area and use appropriate protective equipment to ensure safety during its use in various applications.

Upstream product

• 23055-78-9 bis(4-iodophenyl)methane 
• 611-98-3 4,4'-diaminobenzophenone 
• 38361-32-9 Bis-<4-(diacetoxyiod)phenyl>-methan 
• 591-50-4 iodobenzene 
• 251449-99-7 4,4',4''-triiodotriphenylmethane 
• 5216-55-7 1,1-bis-(4-iodo-phenyl)-ethane 
• 64-19-7 acetic acid 
• 3988-03-2 bis(4-bromophenyl)methanone 
• 101-81-5 Diphenylmethane 

Downstream Products

• 100381-83-7 bis(4-iodophenyl)methanol 
• 329935-60-6 4,4'-diiodo-3,3'-dinitro-benzophenone 
• 854228-28-7 1,1-bis-(4-iodo-phenyl)-2-phenyl-ethanol 
• 856373-04-1 2-(4-chloro-phenyl)-1,1-bis-(4-iodo-phenyl)-ethanol 
• 99512-82-0 4,4'-diiodobenzophenone oxime 
• 2873-76-9 4,4′-bis(diphenylamino)benzophenone 
• 49674-70-6 4,4'-bis(phenylethynyl)benzophenone 
• 31224-78-9 4,4'-bis(phenylglyoxalyl)diphenylketone 
• 182196-75-4 1-(4-{4-[2-Oxo-2-(4-phenoxy-phenyl)-acetyl]-benzoyl}-phenyl)-2-(4-phenoxy-phenyl)-ethane-1,2-dione 
• 182196-74-3 1-(4-{4-[2-Oxo-2-(4-phenylsulfanyl-phenyl)-acetyl]-benzoyl}-phenyl)-2-(4-phenylsulfanyl-phenyl)-ethane-1,2-dione 
• 104881-56-3 4-Diphenylamino-N-diphenylaminophenyl-N-phenylbenzylalkohol 
• 19014-16-5 4,4'-diamino-3,3'-dinitrobenzophenone 
• 6093-44-3 1,1-bis(4-iodophenyl)ethylene 
• 855751-11-0 1,1-bis-(4-iodo-phenyl)-2-phenyl-ethene 

Relevant academic research and scientific papers

Programmable Triboelectric Nanogenerators Dependent on the Secondary Building Units in Cadmium Coordination Polymers

Precisely controlling the coordination microenvironment and electronic features of polynuclear secondary building units (SBUs) in coordination polymers (CPs) is an efficient approach to governing their fundamental performance. Here, different multinuclear

Conformational locking by design: Relating strain energy with luminescence and stability in rigid metal-organic frameworks

Minimization of the torsional barrier for phenyl ring flipping in a metal-organic framework (MOF) based on the new ethynyl-extended octacarboxylate ligand H8TDPEPE leads to a fluorescent material with a near-dark state. Immobilization of the ligand in the rigid structure also unexpectedly causes significant strain. We used DFT calculations to estimate the ligand strain energies in our and all other topologically related materials and correlated these with empirical structural descriptors to derive general rules for trapping molecules in high-energy conformations within MOFs. These studies portend possible applications of MOFs for studying fundamental concepts related to conformational locking and its effects on molecular reactivity and chromophore photophysics.

Dendritic structure having a potential gradient: New synthesis and properties of carbazole dendrimers

A new synthetic route for carbazole dendrimers was discovered using the copper-catalyzed N-arylation reaction. This synthetic route allowed synthesizing the fourth generation carbazole dendrimer and several derivatives for the first time. The crystal structure, Mark-Houwink-Sakurada plots, and UV-vis and fluorescence studies showed that the dendritic carbazole backbone has a rigid and highly twisted structure. From the measurement of the redox potential of the ferrocene derivatives, the IR spectra of the benzophenone derivatives, and complexation behavior of the phenylazomethine derivatives, the inductive electron-withdrawing effect of the carbazole dendron was revealed. This suggested that the summation of this electron withdrawal from each layer may produce a potential gradient such that the outer layer is electron-rich and the inner layer is electron-poor in the carbazole dendron. By assignment of the 1H and 13C NMR spectra of the dendron, the existence of this kind ofpotential gradient was proved. Overall, these data show the ?-polari zation substituent effect of the carbazole unit, and their summation determines the potential gradient in the repeating dendritic structure of the carbazole dendrimer.

Preparation of Complexing Compounds Containing Two 2,6-bis-4-ethynylpyridine Subunits

Compounds containing two 2,6-bis-4-ethynylpyridine subunits have been prepared by coupling reactions between diiodoarenes and acetylenes in the presence of a palladium catalyst and copper(I) iodide.

Inverse Triphenylmethylium Dyes

When in the conventional triphenymethylium dye systems of the crystal violet and malachit green type, 6 and 7, the N-donor and C(+)-acceptor centers are interchanged, the "Inverse Triphenylmethylium Dye Types" 4 and 5 are obtained, showing very similar colors.The stable models with R = phenyl (8 - 10) and R = p-tolyl (11 - 13) were investigated in more detail.The visual observations were supported by the VIS spectra which showed nearly the same longest wavelength absorption maxima for corresponding pairs of inverse and conventional dye representatives.The experimental results can be interpreted with a simple HMO-model according to which the longest wavelength absorptions correspond here to transitions of equal energy from weakly bonding to nonbonding and from nonbonding to weakly antibonding molecular orbitals, respectively.On the same basis numerous isoelectronic variants of that dye type can be envisaged.In the NMR-spectra of the new dyes, characteristically increasing deshieldings of nearly all positions are observed in going from the mono- (10(+), 13(+)) through the di- (9(++), 12(++)) to the trications (8(+++), 11(+++)). - Key words: Dyes, Di-, Tricarbeniumions, NMR Spectra, VIS Spectra