Diazene, bis(3,4-dimethoxyphenyl)-

Base Information

• Chemical Name: Diazene, bis(3,4-dimethoxyphenyl)-
• CAS No.: 31237-07-7
• Molecular Formula: C16H18N2O4
• Molecular Weight: 302.33
• Mol file: 31237-07-7.mol

Synonyms:

Chemical Property of Diazene, bis(3,4-dimethoxyphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diazene, bis(3,4-dimethoxyphenyl)-

There total 8 articles about Diazene, bis(3,4-dimethoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3,4-dimethoxyaniline (6315-89-5) → bis-(3,4-dimethoxy-phenyl)-diazene (31237-07-7)

Guidance literature:

With manganese(IV) oxide; In toluene; Reflux; Inert atmosphere;

DOI:10.1002/adsc.202100440

Reference yield: 20.0%

carbon monoxide (201230-82-2) + 3,4-dimethoxyaniline (6315-89-5) → bis-(3,4-dimethoxy-phenyl)-diazene (31237-07-7) + 1,3-bis-(3,4-dimethoxyphenyl)urea

Guidance literature:

With copper diacetate; air; palladium diacetate; In toluene; for 2h; under 760 Torr; Heating;

DOI:10.1021/jo060612n

Reference yield:

3,4-dimethoxynitrobenzene (709-09-1) → bis-(3,4-dimethoxy-phenyl)-diazene (31237-07-7) + 3,3',4,4'-tetramethoxyazoxybenzene (87587-65-3) + 3,4-dimethoxyaniline (6315-89-5)

Guidance literature:

With triethylamine; In acetonitrile; Rate constant; Product distribution; Mechanism; Ambient temperature; Irradiation;

DOI:10.1021/jo961821i

upstream raw materials:

3,4-dimethoxynitrobenzene

3,3',4,4'-tetramethoxyazoxybenzene

4-azido-1,2-dimethoxybenzene

3,4-dimethoxyaniline

Downstream raw materials:

N,N'-bis-(4,5-dimethoxy-2-nitro-phenyl)-N-nitro-hydrazine

3,4-dimethoxyaniline

Refernces

• 1、 Mustill, Reginald A.,Rees, Alun H.. "Approaches to Azepines: A New Azepine by the Photolysis of Dimethyl p-Azidosalicylate". . p. 5041 - 5043. Retrieved 1983.
• 2、 Orito, Kazuhiko,Miyazawa, Mamoru,Nakamura, Takatoshi,Horibata, Akiyoshi,Ushito, Harumi,Nagasaki, Hideo,Yuguchi, Motoki,Yamashita, Satoshi,Yamazaki, Tetsuro,Tokuda, Masao. "Pd(OAc)2-catalyzed carbonylation of amines". . p. 5951 - 5958. Retrieved 2007/10/03.