Methylene, oxo-

Base Information

• Chemical Name: Methylene, oxo-
• CAS No.: 201230-82-2
• Molecular Formula: CO
• Molecular Weight: 28.0104
• Mol file: 201230-82-2.mol

Synonyms:

Chemical Property of Methylene, oxo-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methylene, oxo-

There total 2359 articles about Methylene, oxo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

methane (34557-54-5,27936-85-2) → carbon monoxide (201230-82-2) + hydrogen (1333-74-0)

Guidance literature:

With oxygen; at 850 ℃; for 24h; under 760.051 Torr; Reagent/catalyst; Temperature; Time; Catalytic behavior; Flow reactor;

DOI:10.1134/S002315841705010X

Reference yield: 61.1%

methane (34557-54-5,27936-85-2) + oxygen (80937-33-3) → carbon monoxide (201230-82-2) + hydrogen (1333-74-0)

Guidance literature:

With catalyst:NiO(12.4)/Ce_0.13Zr_0.87O₂; In neat (no solvent, gas phase); mixt. of 10% CH4, 5% O2, and 85% N2 allowed to flow at SV 120,000 L/(kg h) (reactor - quartz tube, 923 K); detd. by chromy.; Kinetics;

DOI:10.1006/jcat.2001.3249

Reference yield: 58.0%

methane (34557-54-5,27936-85-2) + water (7732-18-5) → carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + hydrogen (1333-74-0)

Guidance literature:

at 800 ℃; under 21281.4 Torr; Product distribution / selectivity; Industry scale;

upstream raw materials:

oxirane

3-methyloxetane

acetone

tetrahydrofuran

Downstream raw materials:

14-Phenyl-12-oxo-tetradecansaeure-methylester

Diethyl-methyl-[2-methyl-cyclohex-(E)-ylidenemethoxy]-silane

1-methyl-1-cyclohexanecarboxylic acid

2-(4-nitrophenyl)propionaldehyde

Refernces

• 1、 Blanco, María B.,Barnes, Ian,Wiesen, Peter,Teruel, Mariano A.. "Atmospheric sink of methyl chlorodifluoroacetate and ethyl chlorodifluoroacetate: Temperature dependent rate coefficients, product distribution of their reactions with Cl atoms and CF2ClC(O)OH formation". . p. 51834 - 51844. Retrieved 2016.
• 2、 Vidyasagar, Devthade,Manwar, Nilesh,Gupta, Akanksha,Ghugal, Sachin G.,Umare, Suresh S.,Boukherroub, Rabah. "Phenyl-grafted carbon nitride semiconductor for photocatalytic CO2-reduction and rapid degradation of organic dyes". . p. 822 - 832. Retrieved 2019.
• 3、 He, Sisi,Ni, Fenglou,Ji, Yujin,Wang, Lie,Wen, Yunzhou,Bai, Haipeng,Liu, Gejun,Zhang, Ye,Li, Youyong,Zhang, Bo,Peng, Huisheng. "The p-Orbital Delocalization of Main-Group Metals to Boost CO2 Electroreduction". . p. 16114 - 16119. Retrieved 2018.
• 4、 Grosse, Philipp,Gao, Dunfeng,Scholten, Fabian,Sinev, Ilya,Mistry, Hemma,Roldan Cuenya, Beatriz. "Dynamic Changes in the Structure, Chemical State and Catalytic Selectivity of Cu Nanocubes during CO2 Electroreduction: Size and Support Effects". . . Retrieved 2018.
• 5、 Li, Hong,Qin, Xianxian,Jiang, Tianwen,Ma, Xian-Yin,Jiang, Kun,Cai, Wen-Bin. "Changing the Product Selectivity for Electrocatalysis of CO2 Reduction Reaction on Plated Cu Electrodes". . p. 6139 - 6146. Retrieved 2019.
• 6、 Wang, Zhi-Qiao,Xu, Zhong-Ning,Peng, Si-Yan,Zhang, Ming-Jian,Lu, Gang,Chen, Qing-Song,Chen, Yumin,Guo, Guo-Cong. "High-performance and long-lived Cu/SiO2 nanocatalyst for CO2 hydrogenation". . p. 4255 - 4259. Retrieved 2015.
• 7、 Li, Xiao-Hong,Fujimoto, Kaoru. "Low Temperature Oxidative Coupling of Methane by Perovskite Oxide". . p. 1581 - 1584. Retrieved 1994.
• 8、 Venter, Jeremy J.,Vannice, M. Albert. "Diffuse Reflectance Infrared Fourier Transform Spectroscopic Investigation of the Decomposition". . p. 4158 - 4167. Retrieved 1989.
• 9、 Pham, Thanh-Dong,Lee, Byeong-Kyu. "Novel photocatalytic activity of Cu@V co-doped TiO2/PU for CO2 reduction with H2O vapor to produce solar fuels under visible light". . p. 87 - 95. Retrieved 2017.
• 10、 Chen, Shuyao,Zhang, Junfeng,Wang, Peng,Wang, Xiaoxing,Song, Faen,Bai, Yunxing,Zhang, Meng,Wu, Yingquan,Xie, Hongjuan,Tan, Yisheng. "Effect of Vapor-phase-treatment to CuZnZr Catalyst on the Reaction Behaviors in CO2 Hydrogenation into Methanol". . p. 1448 - 1457. Retrieved 2019.