Germylene, chlorophenyl-

Base Information

• Chemical Name: Germylene, chlorophenyl-
• CAS No.: 32329-21-8
• Molecular Formula: C6H5ClGe
• Molecular Weight: 185.149
• Mol file: 32329-21-8.mol

Synonyms:

Chemical Property of Germylene, chlorophenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Germylene, chlorophenyl-

There total 2 articles about Germylene, chlorophenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

diazoacetic acid ethyl ester (623-73-4) + phenyldichlorogermane (7366-24-7) → C6H5ClGe (32329-21-8)

Guidance literature:

In neat (no solvent); byproducts: ClCH2CO2CH2CH3, N2; diazoacetate adding dropwise to germane at 0°C to result an immediate N2 evolution; after 24 h at room temp. pentane adding, viscous oilof germylene sepg.; identified as cycloaddition product with dimethylbutadiene;

DOI:10.1016/S0022-328X(00)87639-1

Reference yield:

→ C6H5ClGe (32329-21-8)

Guidance literature:

Aus Ph(Cl2)2GeH;

Reference yield: 88.0%

diethylmercury (627-44-1) + C6H5ClGe (32329-21-8) → phenyldiethylgermane (79301-90-9) + Phenylethylgerman (57539-73-8)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; benzene; to PhGeCl was added Et2Hg, 100°C, 12 h, then mixt. was refluxed in THF with LiAlH4; hydrolysis, products were not sepd.; analyzed by cpv;

upstream raw materials:

diazoacetic acid ethyl ester

phenyldichlorogermane

Downstream raw materials:

(C₆F₅)3Ge(C₆H₅)Ge(CH₂CCH₃)2

triethylchlorogermane

1-Chlor-3,4-dimethyl-1-phenyl-1-germano-cyclopent-3-en

(C₆F₅)3GeGe(C₆H₅)2Ge(C₆F₅)3