1-Phenyl-3-azido-3-methylbutane

Base Information

• Chemical Name: 1-Phenyl-3-azido-3-methylbutane
• CAS No.: 32366-28-2
• Molecular Formula: C11H15N3
• Molecular Weight: 189.26
• Mol file: 32366-28-2.mol

Synonyms:(3-Azido-3-methylbutyl)benzene;2-Azido-2-methyl-4-phenylbutan;(3-Azido-3-methyl-butyl)-benzene;3-azido-3-methylbutylbenzene;

Chemical Property of 1-Phenyl-3-azido-3-methylbutane

Chemical Property:

• PSA: 49.75000
• LogP: 3.16086

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Phenyl-3-azido-3-methylbutane

There total 12 articles about 1-Phenyl-3-azido-3-methylbutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-methyl-4-phenyl-1-butene (6683-51-8) → (3-azido-3-methyl-butyl)-benzene (32366-28-2)

Guidance literature:

With tert.-butylhydroperoxide; tetramethyldisiloxane; cobalt(II) tetrafluoroborate; In decane; ethanol; at 23 ℃; for 7h;

DOI:10.1055/s-2007-1000817

Reference yield: 90.0%

1,1-dimethyl-3-phenylpropyl diphenylphosphinite (820961-79-3) → (3-azido-3-methyl-butyl)-benzene (32366-28-2)

Guidance literature:

With trimethylsilylazide; 2-methoxy-1,4-benzoquinone; In chloroform; at -45 - 20 ℃; for 3h;

DOI:10.1246/cl.2006.1432

Reference yield: 87.0%

2-fluoro-2-methyl-4-phenylbutane (19031-66-4) → (3-azido-3-methyl-butyl)-benzene (32366-28-2)

Guidance literature:

With tris(pentafluorophenyl)borane monohydrate; trimethylsilylazide; In nitromethane; at 23 ℃; for 1h; Sealed tube;

DOI:10.1016/j.jfluchem.2016.11.005

upstream raw materials:

2-chloro-2-methyl-4-phenylbutane

(3-bromo-3-methyl-n-butyl)benzene

2-fluoro-2-methyl-4-phenylbutane

2-methyl-4-phenyl-1-butene

Downstream raw materials:

(3-methylbutyl)benzene

N-methyl-(1-methyl-3-phenylpropylidene)amine

α-methylethylidene-2-phenylethylamine