Borane, tris(2-methyl-2-propenyl)-

Base Information

• Chemical Name: Borane, tris(2-methyl-2-propenyl)-
• CAS No.: 32784-73-9
• Molecular Formula: C12H21B
• Molecular Weight: 176.11
• DSSTox Substance ID: DTXSID80465375
• Nikkaji Number: J916.813C
• Wikidata: Q82291252
• Mol file: 32784-73-9.mol

Synonyms:Borane, tris(2-methyl-2-propenyl)-;trimethallylborane;32784-73-9;DTXSID80465375

Chemical Property of Borane, tris(2-methyl-2-propenyl)-

Chemical Property:

• Boiling Point: 219.8±39.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.755±0.06 g/cm3(Predicted)
• LogP: 4.20950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 176.1736308
• Heavy Atom Count: 13
• Complexity: 175

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: B(CC(=C)C)(CC(=C)C)CC(=C)C

Technology Process of Borane, tris(2-methyl-2-propenyl)-

There total 1 articles about Borane, tris(2-methyl-2-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-Chloro-2-methylpropene (563-47-3) → 2,5-dimethyl-1,5-hexadiene (627-58-7) + tris(2-methyl-2-propenyl)borane (32784-73-9)

Guidance literature:

3-Chloro-2-methylpropene; With magnesium; In diethyl ether;

With boron trifluoride; In diethyl ether;

DOI:10.1021/ja051330s

Reference yield: 96.0%

3-Mercapto-4-{[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-amino}-6-methyl-4H-[1,2,4]triazin-5-one + tris(2-methyl-2-propenyl)borane (32784-73-9) → 4-[4-(4-methoxyphenyl)-2-methylbut-1-en-4-yl]amino-3-mercapto-6-methyl-4H-1,2,4-triazin-5-one

Guidance literature:

With boron trifluoride diethyl etherate; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1002/hc.10144

Reference yield: 95.0%

4-{[1-(4-Chloro-phenyl)-meth-(E)-ylidene]-amino}-3-mercapto-6-methyl-4H-[1,2,4]triazin-5-one + tris(2-methyl-2-propenyl)borane (32784-73-9) → 4-[4-(4-chlorophenyl)-2-methylbut-1-en-4-yl]amino-3-mercapto-6-methyl-4H-1,2,4-triazin-5-one

Guidance literature:

With boron trifluoride diethyl etherate; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1002/hc.10144

upstream raw materials:

3-Chloro-2-methylpropene

Downstream raw materials:

(-)-(S)-2,5-dimethyl-5-hexen-3-ol

4-Methylpent-4-en-1-yne

(2R,6S)-2,6-Bis-(2-methyl-allyl)-1,2,3,6-tetrahydro-pyridine

2,2-bis(2-methylallyl)pyrrolidine