(Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3

Base Information

• Chemical Name: (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3
• CAS No.: 1146360-21-5
• Molecular Formula: CHCl₃*C₆₆H₅₂P₄Pt₂S₄
• Molecular Weight: 1606.84
• Mol file: 1146360-21-5.mol

Synonyms:

Chemical Property of (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3

There total 3 articles about (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(diphenylphosphino)acetylene (5112-95-8) → (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3 (1146360-21-5)

Guidance literature:

Multi-step reaction with 2 steps

1: water; ethanol; benzene

2: chloroform

In ethanol; chloroform; water; benzene;

DOI:10.1039/b815013c

Reference yield:

[Pt2Cl4(1,2-bis(diphenylphosphino)acetylene)2] + 3,4-dimercaptotoluene (496-74-2) + chloroform (67-66-3,8013-54-5) → (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3 (1146360-21-5)

Guidance literature:

In chloroform; (protected from light and air, under Ar); ligand dissolved in CHCl3 added to CHCl3 soln. of Pt-complex, stirred for 2 h; dried under reduced pressure, recrystd. from CHCl3, MeOH or CH2Cl2-MeOH;elem. anal.;

DOI:10.1039/b815013c

Reference yield:

3,4-dimercaptotoluene (496-74-2) + chloroform (67-66-3,8013-54-5) + (Pt(OTf)2)2(μ-1,2-bis(diphenylphosphino)acetylene)2 → (Pt(3,4-toluenedithiolate))2(μ-1,2-bis(diphenylphosphino)acetylene)2*CHCl3 (1146360-21-5)

Guidance literature:

In nitromethane; chloroform; (protected from light and air, under Ar); ligand dissolved in CHCl3 added to nitromethane soln. of Pt-complex, stirred for 2 h; dried under reduced pressure, recrystd. from CHCl3, MeOH or CH2Cl2-MeOH;

DOI:10.1039/b815013c

upstream raw materials:

3,4-dimercaptotoluene

chloroform

bis(diphenylphosphino)acetylene