Cyclohexane, [(4-methyl-1-pentynyl)oxy]-

Base Information

Chemical Name:Cyclohexane, [(4-methyl-1-pentynyl)oxy]-
CAS No.:335197-14-3
Molecular Formula:C12H20O
Molecular Weight:180.29
Hs Code.:

Synonyms:

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Chemical Property of Cyclohexane, [(4-methyl-1-pentynyl)oxy]-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Cyclohexane, [(4-methyl-1-pentynyl)oxy]-

There total 1 articles about Cyclohexane, [(4-methyl-1-pentynyl)oxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 60306-25-4
isobutyl triflate

: 68877-57-6
Cyclohexyl ethynyl ether

: 335197-14-3
(4-methyl-pent-1-ynyloxy)-cyclohexane

Guidance literature:: Cyclohexyl ethynyl ether; With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 0.333333h;

isobutyl triflate; In tetrahydrofuran; dichloromethane; at -60 - 25 ℃; for 12h; Further stages.;
DOI:10.1021/ja004098t

Reference yield: 99.0%

: 335197-14-3
(4-methyl-pent-1-ynyloxy)-cyclohexane

: 335197-16-5
((E)-1-Bromo-4-methyl-pent-1-enyloxy)-cyclohexane

Guidance literature:: With methanol; trimethylsilyl bromide; In dichloromethane; at -20 - 20 ℃;
DOI:10.1021/ja012119t

Reference yield:

: 335197-14-3
(4-methyl-pent-1-ynyloxy)-cyclohexane

: 145075-81-6
3β,16β,17α-trihydroxycholest-5-en-22-one 16-O-{O-[2-O-(4-methoxybenzoyl)-β-D-xylopyranosyl]-(1->3)-2-O-acetyl-β-L-arabinopyranoside}

Guidance literature:: Multi-step reaction with 8 steps

1.1: 99 percent / TMSBr; MeOH / CH₂Cl₂ / -20 - 20 °C

2.1: tert-BuLi; CuCN; LiCl / diethyl ether; tetrahydrofuran / 0.75 h / -78 °C

2.2: tetrahydrofuran / -78 - 25 °C

3.1: t-BuOK / tetrahydrofuran / 0.17 h / 0 °C

3.2: tetrahydrofuran / -30 - 25 °C

4.1: 1.274 g / PPTS / CH₂Cl₂ / 3 h / 25 °C

5.1: KO-t-Bu / tetrahydrofuran / 0.17 h / 0 °C

5.2: 76 percent / Davis reagent / -78 °C

6.1: 97 percent / LiAlH₄ / tetrahydrofuran / 1 h / -78 °C

7.1: 71 percent / TMSOTf; 4 Angstroem molecular sieves / CH₂Cl₂ / 5 h / -20 °C

8.1: DDQ; H₂O / CH₂Cl₂ / 12 h / 25 °C

8.2: 81 percent / Pd(CN)2Cl₂; H₂O / acetone / 2 h / 25 °C

With methanol; lithium aluminium tetrahydride; trimethylsilyl bromide; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; potassium tert-butylate; water; tert.-butyl lithium; pyridinium p-toluenesulfonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium chloride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ja012119t