Chloro(triisopropylphosphine)gold,97%

Base Information

• Chemical Name: Chloro(triisopropylphosphine)gold,97%
• CAS No.: 33659-45-9
• Molecular Formula: C9H21AuClP
• Molecular Weight: 392.659
• Mol file: 33659-45-9.mol

Synonyms:

Chemical Property of Chloro(triisopropylphosphine)gold,97%

Chemical Property:

• Melting Point: 187-191°C

Purity/Quality:

99.90% ^*data from raw suppliers

Chloro(triisopropylphosphine)gold 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 25-36/37/38
• Safety Statements: 26-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of Chloro(triisopropylphosphine)gold,97%

There total 5 articles about Chloro(triisopropylphosphine)gold,97% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

chloroauric acid + tris(1-methylethyl)phosphine (6476-36-4) → [AuCl(PiPr3)] (33659-45-9)

Guidance literature:

In methanol; N2 atmosphere; addn. of soln of org. compd. in MeOH to soln. of Au-compd. in MeOH (0°C), stirring (20 h); pptn. on addn. of H2O, filtration, washing (MeOH), drying (vac.);

Reference yield: 51.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + tris(1-methylethyl)phosphine (6476-36-4) → [AuCl(PiPr3)] (33659-45-9)

Guidance literature:

In tetrahydrofuran; at 20 ℃; Inert atmosphere; Glovebox;

DOI:10.1021/acs.jmedchem.0c01926

Reference yield:

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + tris(1-methylethyl)phosphine (6476-36-4) → [AuCl(PiPr3)] (33659-45-9)

Guidance literature:

In not given; according to R. Uson et al. (1989), vol. 26, p. 85-91;

DOI:10.1021/om049574t

upstream raw materials:

tris(1-methylethyl)phosphine

(tetrahydrothiophene)gold(I) chloride

bis(triphenylphosphine)iminium chloride

chloro(dimethylsulfide) gold(I)

Downstream raw materials:

[AuMo2(cyclopentadienyl)2(μ-PCy2)(CO)2(P(i)Pr3)]

(benzophenoneimine)(triisopropylphosphane)gold(I) tetrafluoroborate

[AuFe2Cp2(μ-PPh2)(CO)2(P(i)Pr3)]

C₆H₅P(S)(SAu(P(CH(CH₃)2)3))2

Refernces

• 1、 Miyamoto, Yukiko,Aggarwal, Shubhangi,Celaje, Jeff Joseph A.,Ihara, Sozaburo,Ang, Jonathan,Eremin, Dmitry B.,Land, Kirkwood M.,Wrischnik, Lisa A.,Zhang, Liangfang,Fokin, Valery V.,Eckmann, Lars. "Gold(I) Phosphine Derivatives with Improved Selectivity as Topically Active Drug Leads to Overcome 5-Nitroheterocyclic Drug Resistance in Trichomonas vaginalis". . p. 6608 - 6620. Retrieved 2021/05/29.
• 2、 Albinati, Alberto,Venanzi, Luigi M.,Wang, Guozhi. "Ruthenium tri- and digold hydride clusters". . p. 3660 - 3669. Retrieved 2008/10/08.