Synonyms:chloro(tetrahydrothiophene)gold(i);39929-21-0;Chlorotetrahydrothiophenegold(I);chlorogold;thiolane;MFCD28411665;C3688
97% *data from raw suppliers
There total 15 articles about Chloro(tetrahydrothiophene)gold(i) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
Reference yield: 98.9%
Reference yield: 98.0%
Reference yield: 96.0%
The research focuses on the synthesis and application of perhalogenated carba-closo-dodecaborate anions as ligand substituents in gold catalysis. The study explores the use of HCB11Cl11? anion (1) as a super-bulky, inert, and charged ligand substituent due to its large van der Waals volume and weakly coordinating properties. The researchers synthesized a phosphine ligand, iPr2P(CB11Cl11)Li? (2), and demonstrated its utility by preparing unique single-component AuI catalysts with unprecedented activity for the hydroamination of alkynes with primary amines. The experiments involved the treatment of the trimethylammonium salt of anion 1 with nBuLi and subsequent quenching with iPr2PCl to afford 2, which was then combined with chloro(tetrahydrothiophene)gold(I) to form the zwitterionic Au complex 3(THT). The catalytic properties of 3 were evaluated in the hydroamination of primary amines with alkynes, showing high activity even at ultra-low catalyst loadings, with the highest reported TON reaching 92000. The study utilized techniques such as 1H and 31P NMR spectroscopy to monitor reactions and X-ray diffraction to confirm the structures of the synthesized compounds.
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