2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl-

Base Information

• Chemical Name: 2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl-
• CAS No.: 33919-00-5
• Molecular Formula: C9H12O3
• Molecular Weight: 168.192
• DSSTox Substance ID: DTXSID00462583
• Nikkaji Number: J1.605.790H
• Mol file: 33919-00-5.mol

Synonyms:33919-00-5;2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl-;SCHEMBL1683958;DTXSID00462583

Chemical Property of 2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl-

Chemical Property:

• XLogP3: 1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 168.078644241
• Heavy Atom Count: 12
• Complexity: 252

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(C=C(C1=O)C)(C)OO

Technology Process of 2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl-

There total 4 articles about 2,5-Cyclohexadien-1-one, 4-hydroperoxy-2,4,6-trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

Mesitol (527-60-6) → 4-hydroperoxy-2,4,6-trimethyl-2,5-cyclohexadien-1-one (33919-00-5)

Guidance literature:

With Oxone; sodium hydrogencarbonate; In water; acetonitrile; at 25 ℃; for 0.833333h;

DOI:10.1002/anie.200504605

Reference yield:

4-hydroxy-2,4,6-trimethyl-cyclohexa-2,5-dienone (16404-66-3) → 2,6-dimethyl-1,4-benzoquinone (527-61-7) + 4-hydroperoxy-2,4,6-trimethyl-2,5-cyclohexadien-1-one (33919-00-5)

Guidance literature:

With K₁₀ montmorillonite; water; dihydrogen peroxide; In tetrachloromethane; at 22 ℃; for 2h;

Reference yield:

Mesitol (527-60-6) → 4-hydroxy-2,4,6-trimethyl-cyclohexa-2,5-dienone (16404-66-3) + 4-hydroperoxy-2,4,6-trimethyl-2,5-cyclohexadien-1-one (33919-00-5)

Guidance literature:

With sodium molybdate; sodium hydroxide; dihydrogen peroxide; In methanol; at 25 ℃; for 7h;

DOI:10.1016/S0040-4039(02)02108-1

upstream raw materials:

Mesitol

4-hydroxy-2,4,6-trimethyl-cyclohexa-2,5-dienone

Downstream raw materials:

4-hydroxy-2,4,6-trimethyl-cyclohexa-2,5-dienone