Trichloro(1-phenylethenyl)silane

Base Information

• Chemical Name: Trichloro(1-phenylethenyl)silane
• CAS No.: 3401-11-4
• Molecular Formula: C8H7Cl3Si
• Molecular Weight: 237.588
• DSSTox Substance ID: DTXSID10500248
• Mol file: 3401-11-4.mol

Synonyms:Trichloro(1-phenylethenyl)silane;3401-11-4;SCHEMBL5482835;DTXSID10500248;1-(phenyl)-1-(trichlorosilyl)-ethylene

Chemical Property of Trichloro(1-phenylethenyl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 235.938260
• Heavy Atom Count: 12
• Complexity: 168

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C(C1=CC=CC=C1)[Si](Cl)(Cl)Cl

Technology Process of Trichloro(1-phenylethenyl)silane

There total 6 articles about Trichloro(1-phenylethenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phenylacetylene (536-74-3) → 1-phenyl-2-(trichlorosilyl)ethane (940-41-0) + 1,1,1-Trichloro-2-phenyl-1-silaprop-2-ene (3401-11-4) + (E)-1-phenyl-2-trichlorosilylethene (3412-59-7)

Guidance literature:

With trichlorosilane; trans-dichloro-bis(ethene)(μ-dichloro)diplatinum(II); at 20 ℃; for 16h;

DOI:10.1021/ja017617g

Reference yield:

phenylacetylene (536-74-3) → styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + ethylbenzene (100-41-4,27536-89-6) + 1,1,1-Trichloro-2-phenyl-1-silaprop-2-ene (3401-11-4) + β-(trichlorosilyl)styrene (1199-94-6)

Guidance literature:

With trichlorosilane; 1,2,4-Triazole; platinum(II) chloride; at 100 ℃; for 5h; Product distribution; oth. catalysts;

Reference yield:

phenylacetylene (536-74-3) → 1,1,1-Trichloro-2-phenyl-1-silaprop-2-ene (3401-11-4) + β-(trichlorosilyl)styrene (1199-94-6)

Guidance literature:

With trichlorosilane; dihydrogen hexachloroplatinate; In tetrahydrofuran; at 110 ℃; for 4h; Product distribution;

upstream raw materials:

1-bromovinylbenzene

phenylacetylene