Silane, trichloro(2-phenylethenyl)-, (E)-

Base Information

• Chemical Name: Silane, trichloro(2-phenylethenyl)-, (E)-
• CAS No.: 3412-59-7
• Molecular Formula: C8H7Cl3Si
• Molecular Weight: 237.588
• Mol file: 3412-59-7.mol

Synonyms:trichlorosilylstyrene;trans styryl trichloro silane;styryltrichlorosilane;E-1-phenyl-2-trichlorosilylethene;(E)-β-trichlorosilylstyrene;(E)-β-(trichlorosilyl)styrene;

Chemical Property of Silane, trichloro(2-phenylethenyl)-, (E)-

Chemical Property:

• Boiling Point: 89-90 °C(Press: 4 Torr)
• PSA: 0.00000
• Density: 1.292±0.06 g/cm3(Predicted)
• LogP: 3.89430

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, trichloro(2-phenylethenyl)-, (E)-

There total 12 articles about Silane, trichloro(2-phenylethenyl)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phenylacetylene (536-74-3) → (E)-1-phenyl-2-trichlorosilylethene (3412-59-7)

Guidance literature:

With trichlorosilane; In benzene; at 20 ℃; for 10h; regioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1039/c7dt00544j

Reference yield: 97.0%

phenylacetylene (536-74-3) → 1-phenyl-2-(trichlorosilyl)ethane (940-41-0) + 1,1,1-Trichloro-2-phenyl-1-silaprop-2-ene (3401-11-4) + (E)-1-phenyl-2-trichlorosilylethene (3412-59-7)

Guidance literature:

With trichlorosilane; trans-dichloro-bis(ethene)(μ-dichloro)diplatinum(II); at 20 ℃; for 16h;

DOI:10.1021/ja017617g

Reference yield: 80.0%

trichlorosilane (10025-78-2) + phenylacetylene (536-74-3) → (E)-1-phenyl-2-trichlorosilylethene (3412-59-7)

Guidance literature:

With dihydrogen hexachloroplatinate; In tetrahydrofuran; isopropyl alcohol; Ambient temperature;

DOI:10.1021/jo00298a043

upstream raw materials:

phenylacetylene

trichlorosilane

styrene

trichlorovinylsilane

Downstream raw materials:

1-(trimethylsilyl)-2-phenylethene

(E)-1-triphenylsilyl-2-phenylethene

(trans-2-phenylethenyl)tris(pentafluorophenyl)silane

(E)-β-(trifluorosilyl)styrene