(S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester

Base Information

Chemical Name:(S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester
CAS No.:34114-96-0
Molecular Formula:C16H28O2
Molecular Weight:252.39200
Hs Code.:
Mol file:34114-96-0.mol

Synonyms:(E)-(S)-3,7,11-Trimethyl-dodeca-6,10-dienoic acid methyl ester;(-)-trans-2,3-dihydro-farnesenic acid methyl ester;

Suppliers and Price of (S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester

Chemical Property:

PSA：26.30000
LogP:4.65850

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester

There total 6 articles about (S,E)-3,7,11-Trimethyl-6,10-dodecadienoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-28-5
Farnesol

: 34114-96-0
methyl (S,E)-2,3-dihydrofarnesenoate

Guidance literature:: Multi-step reaction with 4 steps

1: diacetato[(R)-(+)-2,2-bis(di-p-tolylphosphono)-1,1′?binaphthyl]ruthenium(II); hydrogen / methanol / 5 h / 20 °C / 26252.6 Torr / High pressure; Autoclave

2: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 3 h / 0 - 20 °C

3: sodium dihydrogenphosphate; 2-methyl-but-2-ene; sodium chlorite / tert-butyl alcohol; tetrahydrofuran; water / 3.15 h

4: potassium carbonate / N,N-dimethyl-formamide / 0.5 h

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; diacetato[(R)-(+)-2,2-bis(di-p-tolylphosphono)-1,1′?binaphthyl]ruthenium(II); hydrogen; sulfur trioxide pyridine complex; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol; 2: |Parikh-Doering Oxidation;
DOI:10.1002/ejoc.201800199

Reference yield:

: 20576-54-9,34083-92-6,37519-97-4,51411-24-6,69686-26-6,69743-81-3,76190-00-6,113889-56-8,27745-36-4
(3S)-(6E)-2,3-dihydrofarnesol

: 34114-96-0
methyl (S,E)-2,3-dihydrofarnesenoate

Guidance literature:: Multi-step reaction with 3 steps

1: sulfur trioxide pyridine complex; triethylamine / dichloromethane; dimethyl sulfoxide / 3 h / 0 - 20 °C

2: sodium dihydrogenphosphate; 2-methyl-but-2-ene; sodium chlorite / tert-butyl alcohol; tetrahydrofuran; water / 3.15 h

3: potassium carbonate / N,N-dimethyl-formamide / 0.5 h

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; sulfur trioxide pyridine complex; potassium carbonate; triethylamine; In tetrahydrofuran; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol; 1: |Parikh-Doering Oxidation;
DOI:10.1002/ejoc.201800199

Reference yield:

: 194934-66-2,172376-82-8
(3S)-dihydrofarnesal

: 34114-96-0
methyl (S,E)-2,3-dihydrofarnesenoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium dihydrogenphosphate; 2-methyl-but-2-ene; sodium chlorite / tert-butyl alcohol; tetrahydrofuran; water / 3.15 h

2: potassium carbonate / N,N-dimethyl-formamide / 0.5 h

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; potassium carbonate; In tetrahydrofuran; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1002/ejoc.201800199