(2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate

Base Information

• Chemical Name: (2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate
• CAS No.: 1291074-89-9
• Molecular Formula: C₉₅H₁₀₂IrN₈O₃*F₆P
• Molecular Weight: 1741.09
• Mol file: 1291074-89-9.mol

Synonyms:

Chemical Property of (2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate

There total 1 articles about (2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III) (1291074-49-1) → (2'-(3,5-dimethylpyrazole)-9-O-benzyl-10,11-dihydrocinchonine(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III) hexafluorophosphate (1291074-89-9)

Guidance literature:

In methanol; dichloromethane; byproducts: NH4Cl; under N2; in the dark; CH2Cl2-MeOH added to mixt. of Ir complex and ligand; refluxed for 12 h; cooled to room temp.; NH4PF6 in MeOH added; stirred for 5 h; solvent evapd.; dried under vac.; CH2Cl2 added; filtered; solvent evapd.from filtrate; two diastereomers sepd. by column chromy. (neutral Al2O3 , ethyl acetate-hexane 4:1 and ethyl acetate-MeOH 10:1); two red bands collected; elem. anal.;

DOI:10.1021/om100993u

upstream raw materials:

dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)