dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

Base Information

Chemical Name:dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)
CAS No.:1291074-49-1
Molecular Formula:C₁₂₈H₁₃₂Cl₂Ir₂N₈O₄
Molecular Weight:2301.85
Hs Code.:

Synonyms:

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Chemical Property of dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

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Technology Process of dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

There total 1 articles about dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: iridium(III) chloride hydrate

: 2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine

: 1291074-49-1
dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

Guidance literature:: In 2-ethoxy-ethanol; water; under N2; in the dark; deoxygenated 2-ethoxyethanol-H2O added to mixt. of IrCl3*xH2O and ligand; refluxed at 140°C for 60 h; cooled to room temp.; CH2Cl2 and brine added; CH2Cl2 phase sepd.; washed with brine; dried (anhyd. Na2SO4); solvent removed; purified by column chromy. (neutral Al2O3, ethyl acetate-MeOH 50:1); elem. anal.;
DOI:10.1021/om100993u

Reference yield: 82.0%

: ammonium hexafluorophosphate

: 1291074-49-1
dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

: 13991-08-7
o-phenylenebis(diphenylphosphine)

: 1434584-11-8
[(2′-phenyl-9-O-benzyl-10,11-dihydrocinchonine-C₂,N)₂Ir(1,2-bis(diphenylphosphino)benzene)][PF₆]

Guidance literature:: dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III); o-phenylenebis(diphenylphosphine); In methanol; dichloromethane; for 12h; Inert atmosphere; Schlenk technique; Darkness; Reflux;

ammonium hexafluorophosphate; In methanol; dichloromethane; at 20 ℃; for 15h; Inert atmosphere; Schlenk technique; Darkness;
DOI:10.1021/om400028n

Reference yield: 78.0%

: 1291074-49-1
dichlorotetrakis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))diiridium(III)

: 120-46-7,61346-73-4
1,3-diphenylpropanedione

: (dibenzoylmethane(-1H))bis(2'-phenyl-9-O-benzyl-10,11-dihydrocinchonine(-1H))iridium(III)

Guidance literature:: With K₂CO₃; In 1,2-dichloro-ethane; under N2; in the dark; mixt. of Ir complex, dibenzoylmethane and K2CO3 dissolved in 1,2-dichloroethane; refluxed for 8 h; cooled to room temp.; solvent removed; dissolved in CH2Cl2; org. phase washed with brine; dried (anhyd. Na2SO4); solvent removed; dried under vac.; purified by columnchromy. (neutral Al2O3, ethyl acetate); elem. anal.;
DOI:10.1021/om100993u