ClRu(CO)(triphenylphosphine)2(OC₆H₃(OCH₃)CHN(2-pyridyl))

Base Information

• Chemical Name: ClRu(CO)(triphenylphosphine)2(OC₆H₃(OCH₃)CHN(2-pyridyl))
• CAS No.: 781638-01-5
• Molecular Formula: C₅₀H₄₁ClN₂O₃P₂Ru
• Molecular Weight: 916.358
• Mol file: 781638-01-5.mol

Synonyms:

Chemical Property of ClRu(CO)(triphenylphosphine)2(OC₆H₃(OCH₃)CHN(2-pyridyl))

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ClRu(CO)(triphenylphosphine)2(OC₆H₃(OCH₃)CHN(2-pyridyl))

There total 1 articles about ClRu(CO)(triphenylphosphine)2(OC₆H₃(OCH₃)CHN(2-pyridyl)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + 2-methoxy-6-(E-2-pyridyliminomethyl)phenol (73447-06-0) → ClRu(CO)(triphenylphosphine)2(OC6H3(OCH3)CHN(2-pyridyl)) (781638-01-5)

Guidance literature:

In benzene; adding the Schiff base to benzene soln. of Ru complex (1:1 mol. ratio), heating under reflux for 6 h; concg., cooling, pptn. by addn. of light petroleum ether (60-80°C), filtration, washing the solid, recrystn. from CH2Cl2/light petroleum ether, drying in vac.; elem. anal.;

DOI:10.1016/j.saa.2004.02.011

upstream raw materials:

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

2-methoxy-6-(E-2-pyridyliminomethyl)phenol