Benzenecarbothioic acid, 2-methyl-, S-phenyl ester

Base Information

• Chemical Name: Benzenecarbothioic acid, 2-methyl-, S-phenyl ester
• CAS No.: 35092-37-6
• Molecular Formula: C14H12OS
• Molecular Weight: 228.315
• Mol file: 35092-37-6.mol

Synonyms:

Chemical Property of Benzenecarbothioic acid, 2-methyl-, S-phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenecarbothioic acid, 2-methyl-, S-phenyl ester

There total 15 articles about Benzenecarbothioic acid, 2-methyl-, S-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-methylphenyl aldehyde (529-20-4) + diphenyldisulfane (882-33-7) → 2-Methyl-thiobenzoesaeure-S-phenylester (35092-37-6)

Guidance literature:

With tert.-butylhydroperoxide; potassium carbonate; In water; at 100 ℃; for 2h;

DOI:10.1016/j.cattod.2015.07.010

Reference yield: 98.0%

ortho-methylbenzoic acid (118-90-1) + thiophenol (108-98-5) → 2-Methyl-thiobenzoesaeure-S-phenylester (35092-37-6)

Guidance literature:

With pyridine; O-phenyl phosphorodichloridate; In 1,2-dimethoxyethane; for 16h; Ambient temperature;

Reference yield: 94.0%

2-oxo-2-o-tolylacetic acid + thiophenol (108-98-5) → 2-Methyl-thiobenzoesaeure-S-phenylester (35092-37-6)

Guidance literature:

With dipotassium peroxodisulfate; In water; acetonitrile; at 70 ℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1039/c5ob00769k

upstream raw materials:

ortho-methylbenzoic acid

thiophenol

ortho-toluoyl chloride

diphenyldisulfane

Downstream raw materials:

2-Methyldithiobenzoesaeurephenylester

o-Thiolcarbophenoxybenzylbromid

2-phenyl-1-(o-tolyl)propan-1-one

2-(phenylthio)toluene