(Triphenylplumbyl)triphenylstannane

Base Information

• Chemical Name: (Triphenylplumbyl)triphenylstannane
• CAS No.: 87709-55-5
• Molecular Formula: C₃₆H₃₀PbSn
• Molecular Weight: 788.544
• NSC Number: 170038
• Mol file: 87709-55-5.mol

Synonyms:(triphenylplumbyl)triphenylstannane;NSC170038;87709-55-5;NSC-170038

Chemical Property of (Triphenylplumbyl)triphenylstannane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 790.11361
• Heavy Atom Count: 38
• Complexity: 513

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[Pb](C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of (Triphenylplumbyl)triphenylstannane

There total 1 articles about (Triphenylplumbyl)triphenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

(triphenylplumbyl)lithium (1802-69-3) + triphenyltin chloride (639-58-7) → (C6H5)3PbSn(C6H5)3 (87709-55-5)

Guidance literature:

In tetrahydrofuran; byproducts: Pb2(C6H5)6, LiCl; Ph3PbLi in THF added to a slight excess of Ph3SnCl in THF at - 50 degree.C under N2 within 30 min, stirred at -30 degree.C for 1 h, then at -78 degree.C to freeze out.; Filtered with suction (in air), dried in vac.; dissolved in CHCl3, filtered, light petroleum added; elem. anal., MS, IR, NMR, Raman, X-ray structure.;

DOI:10.1016/0022-328X(84)80356-3

upstream raw materials:

(triphenylplumbyl)lithium

triphenyltin chloride

Refernces