CID 9821512

Base Information

• Chemical Name: CID 9821512
• CAS No.: 639-58-7
• Molecular Formula: C18H15ClSn
• Molecular Weight: 385.48
• Hs Code.: 29310095
• Mol file: 639-58-7.mol

Synonyms:SCHEMBL7180539;T0447

Chemical Property of CID 9821512

Chemical Property:

• Appearance/Colour: colourless solid
• Vapor Pressure: 3.72E-06mmHg at 25°C
• Melting Point: 103-108 °C
• Boiling Point: 397.125 °C at 760 mmHg
• Flash Point: 199.683 °C
• PSA: 0.00000
• Density: 1.49 g/cm3 (20oC)
• LogP: 2.89230
• Storage Temp.: APPROX 4°C
• Sensitive.: Moisture Sensitive
• Solubility.: 0.04g/l
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 385.988431
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

99% ^*data from raw suppliers

Chlorotriphenylstannane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N,C
• Hazard Codes: T,N,C
• Statements: 23/24/25-50/53-34
• Safety Statements: 26-27-28-45-60-61-28A-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+](C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]
• Uses: Chlorotriphenylstannane is used in the synthesis of nanoparticles which bear triamide ligands. Triphenyltin chloride is an important organic intermediate. It is used in agrochemical, pharmaceutical and dyestuff field.

Technology Process of CID 9821512

There total 154 articles about CID 9821512 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

tetraphenyltin(IV) (595-90-4) + tin(IV) chloride (7646-78-8) → triphenyltin chloride (639-58-7)

Guidance literature:

Gallium trichloride;

Reference yield: 90.0%

triphenyllead(IV) chloride (1153-06-6) + diphenyltin(IV) dichloride (1135-99-5) → triphenyltin chloride (639-58-7)

Guidance literature:

In chloroform-d1; at 80 ℃; for 12h; Sealed tube; Inert atmosphere;

DOI:10.1039/c7dt04520d

Reference yield: 85.0%

bis(dichloroboryl)-1,1-ethane (88870-83-1) + tetraphenyltin(IV) (595-90-4) → 1,1-bis(chloro-phenyl-boryl)ethane (934750-71-7) + triphenyltin chloride (639-58-7)

Guidance literature:

In neat (no solvent); (Ar); std. Schlenk technique; mixt. of B compd. and Ph4Sn was stirred atambient temp. for 2 h; heated at 80°C overnight; distd. (100-115°C/0.10 Torr);

DOI:10.1021/om061091x

upstream raw materials:

chloroform

tetraphenyltin(IV)

methylene chloride

triphenylstannane

Downstream raw materials:

2-triphenylstannyl-ethanol

ethyltriphenylstannate

(C₆H₅)3SnC₆H₄-p-N(CH₃)2

cyclohexyltriphenyltin

Refernces

• 1、 D?lling, Karin. "Synthesis and reactivity of β-stannylated phenylalanines". . p. 3 - 16. Retrieved 2017.
• 2、 Domazetis, G.,Magee, R. J.,James, B. D.. "". . p. L48 - L50. Retrieved 1979.
• 3、 Kaplan. "". . p. 1833. Retrieved 1966.
• 4、 Cardin, Christine J.,Roy, Abhijit. "". . p. 57 - 62. Retrieved 1985.
• 5、 ?vec, Petr,?erno?ková, Eva,Padělková, Zdeňka,R??i?ka, Ale,Hole?ek, Jaroslav. "Tri- and diorganostannates containing 2-(N,N-dimethylaminomethyl)phenyl ligand". . p. 2475 - 2485. Retrieved 2010/11/16.