3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester

Base Information

• Chemical Name: 3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester
• CAS No.: 355121-57-2
• Molecular Formula: C16H17BrO4
• Molecular Weight: 353.213
• DSSTox Substance ID: DTXSID001203835
• Mol file: 355121-57-2.mol

Synonyms:ICCB1_000151;SCHEMBL6894689;VUCIOGKPUWDSLC-UHFFFAOYSA-N;DTXSID001203835;3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester;2-Propen-1-yl 4-bromo-3,5-bis(2-propen-1-yloxy)benzoate;355121-57-2

Chemical Property of 3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester

Chemical Property:

• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 10
• Exact Mass: 352.03102
• Heavy Atom Count: 21
• Complexity: 347

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCOC1=CC(=CC(=C1Br)OCC=C)C(=O)OCC=C

Technology Process of 3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester

There total 1 articles about 3,5-Bis-allyloxy-4-bromo-benzoic acid allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

3,5-dihydroxy-4-bromobenzoic acid (16534-12-6) + allyl bromide (106-95-6) → 3,5-bis-allyloxy-4-bromo-benzoic acid allyl ester (355121-57-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 15h;

DOI:10.1021/ja016093h

Reference yield: 47.0%

3,5-bis-allyloxy-4-bromo-benzoic acid allyl ester (355121-57-2) → (3,5-bis-allyloxy-4-bromo-phenyl)-methanol (355121-58-3)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 2h;

DOI:10.1021/ja016093h

Reference yield: 47.0%

3,5-bis-allyloxy-4-bromo-benzoic acid allyl ester (355121-57-2) + aqueous potassium sodium tartrate → (3,5-bis-allyloxy-4-bromo-phenyl)-methanol (355121-58-3)

Guidance literature:

In tetrahydrofuran; water;

upstream raw materials:

3,5-dihydroxy-4-bromobenzoic acid

allyl bromide

Downstream raw materials:

(3,5-bis-allyloxy-4-bromo-phenyl)-methanol

3,5-bis-allyloxy-4-bromo-benzaldehyde

4[(S)-2-(3,5-bis-allyloxy-4-bromo-benzylamino)-3-(triisopropyl-silanyloxy)-propyl]-phenol

carbonic acid allyl ester 4-[(S)-2-[allyloxycarbonyl-(3,5-bis-allyloxy-4-bromo-benzyl)-amino]-3-(triisopropyl-silanyloxy)-propyl]-phenyl ester