BROMOMETHYL PHENYL SULFIDE

Base Information

• Chemical Name: BROMOMETHYL PHENYL SULFIDE
• CAS No.: 35572-08-8
• Molecular Formula: C7H7BrS
• Molecular Weight: 203.103
• Mol file: 35572-08-8.mol

Synonyms:4-Bromomethylthiobenzene;[(bromomethyl)thio]benzene;bromomethyl phenyl sulfide;

Chemical Property of BROMOMETHYL PHENYL SULFIDE

Chemical Property:

• PSA: 25.30000
• LogP: 3.13110

Purity/Quality:

99% ^*data from raw suppliers

BROMOMETHYL PHENYL SULFIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BROMOMETHYL PHENYL SULFIDE

There total 8 articles about BROMOMETHYL PHENYL SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + thiophenol (108-98-5) → bromomethyl phenyl thioether (35572-08-8)

Guidance literature:

With hydrogen bromide; acetic acid; at 20 ℃;

DOI:10.1039/c8ra04002h

Reference yield: 60.0%

trans-[chloro(phenylthiomethyl)bis(triphenylphosphine)platinum(II) (71520-84-8) → phenylthiomethyl chloride (7205-91-6) + diiodobis(triphenylphosphine)platinum(II) (23523-31-1,35085-01-9,35085-00-8) + (P(C6H5)3)2PtICl + bromomethyl phenyl thioether (35572-08-8)

Guidance literature:

In chloroform-d1; byproducts: Br2; addn. of halogen to soln. of complex; amts. of products detected by (1)H-NMR;

DOI:10.1016/S0022-328X(00)99112-5

Reference yield: 57.0%

thiophenoxymethyl bis(dimethyl glyoximato)pyridine cobalt(III) → (4-Br-C6H4SCH2) bis(dimethyl glyoximato)pyridine cobalt(III) + bromomethyl phenyl thioether (35572-08-8)

Guidance literature:

With bromine; In chloroform; addn. of soln. of Br2 in CHCl3 to soln. of Co-compd. in CHCl3 (darkness, room temp., N2 atmosphere, 45 min); concn., pouring into ether, filtration, washing (ether), chromy. (silica gel, CH2Cl2:MeOH:pyridine 90:9:1 vol/vol);

DOI:10.1016/S0020-1693(00)85262-7

upstream raw materials:

(phenylsulfanylmethyl)trimethylsilane

benzoyloxymethylthiobenzene

bromomethyl phenyl sulfoxide

sodium diethyl phosphite

Downstream raw materials:

2-phenylthiomethyl-3-methyl-3-sulfolene

1-(4-chlorophenylsulfenyl)methyl-5-phenylsulphenyl-2(1H)-pyrimidinone

5-iodo-12-phenylsulfenylmethyl-2(1H)-pyrimidinone

2-Phenyl-3-phenylsulfanyl-2-pyrazin-2-yl-propionitrile