1,3-Bis(bromomethyl)naphthalene

Base Information

• Chemical Name: 1,3-Bis(bromomethyl)naphthalene
• CAS No.: 36015-77-7
• Molecular Formula: C₁₂H₁₀Br₂
• Molecular Weight: 314.019
• DSSTox Substance ID: DTXSID40368010
• Nikkaji Number: J2.045.502K
• Wikidata: Q82154285
• Mol file: 36015-77-7.mol

Synonyms:1,3-bis(bromomethyl)naphthalene;36015-77-7;SCHEMBL17986704;DTXSID40368010;AKOS030748453;Z56756161

Chemical Property of 1,3-Bis(bromomethyl)naphthalene

Chemical Property:

• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 313.91288
• Heavy Atom Count: 14
• Complexity: 181

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=C(C=C2CBr)CBr

Technology Process of 1,3-Bis(bromomethyl)naphthalene

There total 1 articles about 1,3-Bis(bromomethyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.8%

1,3-dimethylnaphthalene (575-41-7) → 1,3-bis(bromomethyl)naphthalene (36015-77-7) + 1-(bromomethyl)-3-methylnaphthalene (64977-27-1) + 2-bromomethyl-4-methylnaphthalene (64977-28-2)

Guidance literature:

With N-Bromosuccinimide; In tetrachloromethane; for 48h; Heating;

Reference yield: 7.0%

1,3-bis(bromomethyl)naphthalene (36015-77-7) + 1-<(p-Tolylsulfonyl)amino>-3-benzenethiol (90970-23-3) → N-(p-Tolylsulfonyl)-1-thia-12-aza<2>(1,3)naphthalino<2>metacyclophan (122722-08-1,122697-65-8,122697-66-9) + N-(p-Tolylsulfonyl)-1-thia-12-aza<2>(2,4)naphthalino<2>metacyclophan (122697-59-0,122697-63-6,122697-64-7)

Guidance literature:

With cesium hydroxide; In ethanol; water; acetonitrile; benzene; for 3h; Heating;

Reference yield: 3.0%

1,3-bis(bromomethyl)naphthalene (36015-77-7) + benzyl bromide (100-39-0) → O-benzyl 1-benzylthio-thiocarbonyl-naphthalene-3-carbothioate (1243191-52-7)

Guidance literature:

1,3-bis(bromomethyl)naphthalene; With octasulfur; sodium methylate; In methanol; for 4h; Reflux;

benzyl bromide; In methanol; water; at 20 ℃; Cooling with ice;

DOI:10.1080/10426507.2010.490151

upstream raw materials:

1,3-dimethylnaphthalene

Downstream raw materials:

N-(p-Tolylsulfonyl)-1-thia-12-aza<2>(1,3)naphthalino<2>metacyclophan

N-(p-Tolylsulfonyl)-1-thia-12-aza<2>(2,4)naphthalino<2>metacyclophan

Naphthalin-1,3-dialdehyd

1,3-bis(mercaptomethyl)naphthalene