2-Butanone, 1,1,1-trichloro-3,3-dimethyl-

Base Information

Chemical Name:2-Butanone, 1,1,1-trichloro-3,3-dimethyl-
CAS No.:36965-30-7
Molecular Formula:C6H9Cl3O
Molecular Weight:203.496
Hs Code.:
DSSTox Substance ID:DTXSID50450076

Synonyms:36965-30-7;2-Butanone, 1,1,1-trichloro-3,3-dimethyl-;SCHEMBL5320589;DTXSID50450076

Suppliers and Price of 2-Butanone, 1,1,1-trichloro-3,3-dimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Butanone, 1,1,1-trichloro-3,3-dimethyl-

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:201.971898
Heavy Atom Count:10
Complexity:140

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)C(=O)C(Cl)(Cl)Cl

Technology Process of 2-Butanone, 1,1,1-trichloro-3,3-dimethyl-

There total 1 articles about 2-Butanone, 1,1,1-trichloro-3,3-dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-97-8
3,3-dimethyl-butan-2-one

: 13547-70-1
1-chloro-3,3-dimethyl-butan-2-one

: 22591-21-5
1,1-dichloro-3,3-dimethylbutan-2-one

: 35039-88-4
1,4-dichloro-3,3-dimethyl-butan-2-one

: 3205-31-0
2,2,5,6,6-pentamethyl-hept-4-en-3-one

: 36965-30-7
3,3-dimethyl-1,1,1-trichloro-2-butanone

: 35039-89-5
1,1,4-trichloro-3,3-dimethyl-butan-2-one

: 13104-53-5
4-chloro-3,3-dimethylbutane-2-one

: 35039-91-9
1,4-dichloro-3-chloromethyl-3-methyl-butan-2-one

: 35039-92-0
1,1,4,4-tetrachloro-3,3-dimethyl-butan-2-one

: 35039-93-1
1,1,4-trichloro-3-chloromethyl-3-methyl-butan-2-one

: 1,1,1,4-tetrachloro-3-methyl-3-(chloromethyl)butan-2-one

: 1,1,4-trichloro-3,3-bis-(chloromethyl)butan-2-one

: C₆H₆Cl₆O

: C₆H₆Cl₆O

: 1,1,1,4,4-pentachloro-3,3-bis(chloromethyl)butane-2-one

: 1,1,1,4,4,4-hexachloro-3-(dichloromethyl)-3-(chloromethyl)butane-2-one

Guidance literature:: With chlorine; In tetrachloromethane; for 1h; Irradiation;
DOI:10.1134/S0022476613030050

Reference yield:

: 36965-30-7
3,3-dimethyl-1,1,1-trichloro-2-butanone

: 20859-02-3
L-tert-Leucine

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / (S)-α,α-diphenylprolinol - n-butylboronic acid, catecholborane / toluene / 56 h / -20 °C

2: 80 percent / NaN₃, NaOH, H₂O / 1,2-dimethoxy-ethane / 24 h / 23 °C

3: H₂ / 10percent Pd/C / ethyl acetate / 13 h / 760 Torr

With sodium hydroxide; sodium azide; (S)-diphenylprolinol; butylboronic acid; water; hydrogen; benzo[1,3,2]dioxaborole; palladium on activated charcoal; In 1,2-dimethoxyethane; ethyl acetate; toluene;
DOI:10.1021/ja00031a069

Reference yield:

: 36965-30-7
3,3-dimethyl-1,1,1-trichloro-2-butanone

: 2245-30-9,40102-55-4,62137-90-0,41796-67-2
(R)-tert-butyloxirane

Guidance literature:: Multi-step reaction with 3 steps

1: cathecolborane / (5S)-2-(n-butyl)-4,4-diphenyl-3,2,1-oxazaborabicyclo<3.3.0>octane / toluene / 12 h / -78 °C

2: NaBH₃CN, AIBN, Bu₃SnCl / ethanol / Heating

3: 1) DBU, 2) quinoline / 1) 18 deg C, 2 h, 2) 60 to 70 deg C

With quinoline; 2,2'-azobis(isobutyronitrile); tributyltin chloride; sodium cyanoborohydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; benzo[1,3,2]dioxaborole; (5S)-2-(n-butyl)-4,4-diphenyl-3,2,1-oxazaborabicyclo<3.3.0>octane; In ethanol; toluene;
DOI:10.1016/S0040-4039(00)73959-1