Benzoic acid, 2-(4-carboxyphenoxy)-

Base Information

• Chemical Name: Benzoic acid, 2-(4-carboxyphenoxy)-
• CAS No.: 37407-16-2
• Molecular Formula: C14H10O5
• Molecular Weight: 258.23
• Mol file: 37407-16-2.mol

Synonyms:(2-Carboxy-phenyl)-(4-carboxy-phenyl)-aether;2,4'-oxy-di-benzoic acid;4-(2-Carboxy-phenoxy)-benzoesaeure;Diphenylaether-dicarbonsaeure-(2.4');Benzoic acid,2-(4-carboxyphenoxy);2,4'-Oxy-di-benzoesaeure;

Chemical Property of Benzoic acid, 2-(4-carboxyphenoxy)-

Chemical Property:

• PSA: 83.83000
• LogP: 2.87530

Purity/Quality:

99% ^*data from raw suppliers

2-(4-Carboxyphenoxy)benzoic acid 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 2-(4-carboxyphenoxy)-

There total 10 articles about Benzoic acid, 2-(4-carboxyphenoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-(4-Ethylphenoxy)benzoesaeure (108060-50-0) → 2-(4'-carboxy-phenoxy)benzoic acid (37407-16-2)

Guidance literature:

With potassium permanganate; In water; for 8h; Reflux;

DOI:10.1039/c1ob05072a

Reference yield: 85.0%

2-(4-methylphenoxy)-benzoic acid (21905-69-1) → 2-(4'-carboxy-phenoxy)benzoic acid (37407-16-2)

Guidance literature:

With potassium hydroxide; potassium permanganate;

DOI:10.1002/(SICI)1521-4184(199805)331:5<177::AID-ARDP177>3.0.CO;2-K

Reference yield:

ortho-chlorobenzoic acid (118-91-2) → 2-(4'-carboxy-phenoxy)benzoic acid (37407-16-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 46.6 percent / K₂CO₃, CuI, copper bronze / 3 h / 200 °C

2: 85 percent / KMnO₄, KOH

With potassium hydroxide; potassium permanganate; copper(l) iodide; copper; potassium carbonate;

DOI:10.1002/(SICI)1521-4184(199805)331:5<177::AID-ARDP177>3.0.CO;2-K

upstream raw materials:

1-methyl-2-(4-methylphenoxy)benzene

2-(4-methylphenoxy)-benzoic acid

p-cresol

ortho-chlorobenzoic acid

Downstream raw materials:

Ni(2-(4-carboxyphenoxy)benzoic acid^(2-))(1,10-phenanthroline)

2,4'-oxy-di-benzoyl chloride

9-oxo-9H-xanthene-2-carboxylic acid