Magnesium ethyl malonate

Base Information

• Chemical Name: Magnesium ethyl malonate
• CAS No.: 37517-78-5
• Molecular Formula: C5H8O4.1/2Mg
• Molecular Weight: 286.521
• Hs Code.: 2918990090
• Mol file: 37517-78-5.mol

Synonyms:3-ethoxy-3-oxo-propanoic acid magnesium salt;ethyl hydrogen malonate magnesium salt;malonic acid monoethyl ester magnesium salt;Maleinsaeure-n-hexadecylmonoester;

Chemical Property of Magnesium ethyl malonate

Chemical Property:

• Boiling Point: 132 °C(Press: 20 Torr)
• PSA: 66.43000
• LogP: -1.31050

Purity/Quality:

97% ^*data from raw suppliers

Magnesium3-ethoxy-3-oxopropanoate 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Magnesium ethyl malonate

There total 5 articles about Magnesium ethyl malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

hydrogen ethyl malonate (1071-46-1) → magnesium bis(3-ethoxy-3-oxopropanoate) (37517-78-5)

Guidance literature:

With magnesium(II) chloride hexahydrate; potassium hydroxide; In water; Cooling with ice;

DOI:10.1021/ja106416g

Reference yield: 98.0%

ethyl potassium malonate (6148-64-7) → magnesium bis(3-ethoxy-3-oxopropanoate) (37517-78-5)

Guidance literature:

With magnesium(II) chloride hexahydrate; In water; at 20 ℃; for 0.5h;

DOI:10.1039/c5ob02110c

Reference yield:

hydrogen ethyl malonate (1071-46-1) + magnesium ethylate (2414-98-4) → magnesium bis(3-ethoxy-3-oxopropanoate) (37517-78-5)

Guidance literature:

In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1021/jo01311a047

upstream raw materials:

hydrogen ethyl malonate

magnesium ethylate

ethyl potassium malonate

diethyl malonate

Downstream raw materials:

ethyl 5-(4,5-diphenyl-2-oxazolyl)pentan-3-onate

ethyl 3-(benzo[d][1,3]dioxol-5-yl)-3-oxopropanoate

β-oxo-1-phenylcyclopentanepropanoic acid ethyl ester

ethyl 3-oxododecanoate