Chloro(nonafluoro)cyclopentane

Base Information

• Chemical Name: Chloro(nonafluoro)cyclopentane
• CAS No.: 376-76-1
• Molecular Formula: C5ClF9
• Molecular Weight: 266.494
• Hs Code.: 2902190000
• DSSTox Substance ID: DTXSID70456712
• Wikidata: Q82279269
• Mol file: 376-76-1.mol

Synonyms:376-76-1;Chloro(nonafluoro)cyclopentane;1-Chloro-1,2,2,3,3,4,4,5,5-nonafluorocyclopentane;CHLOROPERFLUOROCYCLOPENTANE;SCHEMBL4828412;DTXSID70456712;MYVQKOLPIBOMHY-UHFFFAOYSA-N

Chemical Property of Chloro(nonafluoro)cyclopentane

Chemical Property:

• PSA: 0.00000
• LogP: 3.44580
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 0
• Exact Mass: 265.9544812
• Heavy Atom Count: 15
• Complexity: 269

Purity/Quality:

99% ^*data from raw suppliers

Chloroperfluorocyclopentane 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1(C(C(C(C1(F)F)(F)Cl)(F)F)(F)F)(F)F

Technology Process of Chloro(nonafluoro)cyclopentane

There total 3 articles about Chloro(nonafluoro)cyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.2%

cyclopentyl chloride (930-28-9) → perfluoropentane (678-26-2) + decafluorocyclopentane (376-77-2) + 1-chlorononafluorocyclopentane (376-76-1) + 3-Chloro-F-pentane (90398-73-5)

Guidance literature:

With fluorine; at -30 - 10 ℃; Further byproducts given. Yields of byproduct given; Irradiation; steady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation;

DOI:10.1021/jo00189a014

Reference yield: 40.2%

cyclopentyl chloride (930-28-9) → perfluoropentane (678-26-2) + 1-Chloro-F-pentane (375-71-3) + decafluorocyclopentane (376-77-2) + 2-Chloro-F-pentane (43216-18-8) + 1-chlorononafluorocyclopentane (376-76-1) + 3-Chloro-F-pentane (90398-73-5)

Guidance literature:

With fluorine; at -30 - 10 ℃; Mechanism; Product distribution; Irradiation; steady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation;

DOI:10.1021/jo00189a014

Reference yield:

1,2-dichloro-3,3,4,4,5,5-hexafluorocyclopentene (706-79-6) → 1,1-dichloro octafluorocyclopentane + nonafluorocyclopentane (376-65-8) + octaperfluorocyclopentene (559-40-0) + 1,2-dichlorooctafluorocyclopentane (376-75-0) + 1,2,2,3,3,4,4-heptafluoro-5-chlorocyclopentene (1759-63-3) + 1-chlorononafluorocyclopentane (376-76-1) + 1,1,2,2,3,3,4-heptafluorocyclopentane (15290-77-4)

Guidance literature:

With hydrogen fluoride; chlorine; at 400 ℃;

DOI:10.1016/j.jfluchem.2016.04.006

upstream raw materials:

cyclopentyl chloride

1,2-dichloro-3,3,4,4,5,5-hexafluorocyclopentene