2-Propenoic acid, 3,3'-(1,3-phenylene)bis-

Base Information

• Chemical Name: 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-
• CAS No.: 37710-81-9
• Molecular Formula: C12H10O4
• Molecular Weight: 218.209
• DSSTox Substance ID: DTXSID90354206
• Mol file: 37710-81-9.mol

Synonyms:2-Propenoic acid, 3,3'-(1,3-phenylene)bis-;CBMicro_016818;m-phenylenediacrylic acid;m-phenylene diacrylic acid;3-[3-(2-carboxyethenyl)phenyl]prop-2-enoic acid;DTXSID90354206;KRXUBZPHAPGHPE-UHFFFAOYSA-N

Chemical Property of 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-

Chemical Property:

• XLogP3: 2.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 218.05790880
• Heavy Atom Count: 16
• Complexity: 287

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC(=C1)C=CC(=O)O)C=CC(=O)O

Technology Process of 2-Propenoic acid, 3,3'-(1,3-phenylene)bis-

There total 1 articles about 2-Propenoic acid, 3,3'-(1,3-phenylene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Isophthalaldehyde (626-19-7) + malonic acid (141-82-2) → 1,3-phenylene-3,3′-bis(2-propenoic) acid (37710-81-9)

Guidance literature:

With pyridine; In toluene; at 80 ℃; for 3h;

Reference yield: 92.0%

1,3-phenylene-3,3′-bis(2-propenoic) acid (37710-81-9) + dimethyl 5-aminoisophthalate (99-27-4) → C32H28N2O10

Guidance literature:

1,3-phenylene-3,3′-bis(2-propenoic) acid; dimethyl 5-aminoisophthalate; With pyridine; for 0.25h;

With triphenyl phosphite; for 8h; Reflux;

DOI:10.1002/chem.201802829

Reference yield: 90.3%

1,3-phenylene-3,3′-bis(2-propenoic) acid (37710-81-9) + acetic acid (64-19-7,77671-22-8) → 2',3',2'',3''-tetrabromo-m-phenylene-di-propionate dimethyl ester (860517-17-5)

Guidance literature:

With bromine; at 40 ℃; for 3h;

upstream raw materials:

Isophthalaldehyde

malonic acid

Downstream raw materials:

3,3′-(1,3-phenylene)dipropionic acid

1,3-bis[(E)-2-bromovinyl]benzene

3-(3-(3-hydroxypropyl)phenyl)propanol

3,3'-m-phenylene-di-propionic acid dimethyl ester