Benzoic acid, 4-(trifluoromethyl)-, silver(1+) salt

Base Information

• Chemical Name: Benzoic acid, 4-(trifluoromethyl)-, silver(1+) salt
• CAS No.: 3794-61-4
• Molecular Formula: C8H5F3O2.Ag
• Molecular Weight: 296.982
• Mol file: 3794-61-4.mol

Synonyms:

Chemical Property of Benzoic acid, 4-(trifluoromethyl)-, silver(1+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzoic acid, 4-(trifluoromethyl)-, silver(1+) salt

There total 1 articles about Benzoic acid, 4-(trifluoromethyl)-, silver(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-trifluoromethylbenzoic acid (455-24-3) + silver(l) oxide (20667-12-3) → silver 4-trifluoromethylbenzoate (3794-61-4)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h; Darkness;

DOI:10.1021/jacs.7b13305

Reference yield: 100.0%

silver 4-trifluoromethylbenzoate (3794-61-4) + PdITol(2,2'-bipyridine) (675201-60-2) → Pd(O2CC6H4CF3)Tol(2,2'-bipyridine) (675201-56-6)

Guidance literature:

In dichloromethane; silver aroate was added to suspn. PdITol(bpy) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo;

DOI:10.1021/om030644q

Reference yield: 99.0%

silver 4-trifluoromethylbenzoate (3794-61-4) + methyl-iod-(N,N,N',N'-tetramethylethanediamine)palladium(II) → Pd(O2CC6H4CF3)Me(N,N,N',N'-tetramethylethylenediamine) (675201-50-0)

Guidance literature:

In dichloromethane; silver aroate was added to suspn. PdIMe(tmeda) in CH2Cl2 and stirred for15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo;

DOI:10.1021/om030644q

upstream raw materials:

4-trifluoromethylbenzoic acid

silver(l) oxide

Downstream raw materials:

fac-Pd(O₂CC₆H₄F₃)Me₃(2,2'-bipyridine)

fac-Pd(O₂CC₆H₄CF₃)Me₃(N,N,N',N'-tetramethylethylenediamine)

Pd(O₂CC₆H₄CF₃)Me(2,2'-bipyridine)

Pd(O₂CC₆H₄CF₃)Me₂Tol(2,2'-bipyridine)