2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-

Base Information

Chemical Name:2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-
CAS No.:381665-55-0
Molecular Formula:C47H73O9PSi3
Molecular Weight:897.321
Hs Code.:

2H-Pyran-2-one,
6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13
-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri
ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-

Synonyms:

Suppliers and Price of 2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-

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Chemical Property of 2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)-

There total 14 articles about 2H-Pyran-2-one, 6-[(1E,3R,4R,6R,7Z,9Z,11E)-6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-13 -[[(1,1-dimethylethyl)diphenylsilyl]oxy]-3-methyl-4-(phosphonooxy)-3-[(tri ethylsilyl)oxy]-1,7,9,11-tridecatetraenyl]-5,6-dihydro-, (6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 500702-54-5
diallyl (1R,3R,4Z,6Z,8E)-3-{[tert-butyl(dimethyl)silyl]oxy}-10-{[tert-butyl(diphenyl)silyl]oxy}-1-{(1R)-1-methyl-3-[(2R)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-[(triethylsilyl)oxy]allyl}deca-4,6,8-trien-1-yl phosphate

: 381665-55-0
Phosphoric acid mono-{(4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl} ester

Guidance literature:: With triphenylphosphine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran;
DOI:10.1039/b209742g

Reference yield:

: 381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one

: 381665-55-0
Phosphoric acid mono-{(4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl} ester

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / Pd(MeCN)2Cl₂ / dimethylformamide / 0 °C

2: tetrazole / CH₂Cl₂ / 0 °C

3: t-BuOOH / CH₂Cl₂ / 0 °C

4: HCO₂NH₂; PPh₃ / Pd(PPh₃)4 / tetrahydrofuran

With 1H-tetrazole; tert.-butylhydroperoxide; triphenylphosphine; dichloro bis(acetonitrile) palladium(II); tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1039/b209742g

Reference yield:

: 381665-45-8
(6R)-6-{(1E,3R,4R,6R,7Z,9Z,11E)-6-{[tert-butyl(dimethyl)silyl]oxy}-13-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxy-3-methyl-3-[(triethylsilyl)oxy]trideca-1,7,9,11-tetraen-1-yl}-5,6-dihydro-2H-pyran-2-one

: 381665-55-0
Phosphoric acid mono-{(4Z,6Z,8E)-(1R,3R)-3-(tert-butyl-dimethyl-silanyloxy)-10-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-1-methyl-3-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-triethylsilanyloxy-allyl]-deca-4,6,8-trienyl} ester

Guidance literature:: Multi-step reaction with 3 steps

1: tetrazole / CH₂Cl₂ / 0 °C

2: t-BuOOH / CH₂Cl₂ / 0 °C

3: HCO₂NH₂; PPh₃ / Pd(PPh₃)4 / tetrahydrofuran

With 1H-tetrazole; tert.-butylhydroperoxide; triphenylphosphine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane;
DOI:10.1039/b209742g