Lithium, (methyldiphenylsilyl)-

Base Information

Chemical Name:Lithium, (methyldiphenylsilyl)-
CAS No.:3839-30-3
Molecular Formula:C13H13LiSi
Molecular Weight:204.273
Hs Code.:
DSSTox Substance ID:DTXSID60448808
Mol file:3839-30-3.mol

Synonyms:Lithium, (methyldiphenylsilyl)-;Ph2MeSiLi;3839-30-3;lithium methyl(diphenyl)silanide;DTXSID60448808;ZEPHIAQDKZSLQK-UHFFFAOYSA-N

Suppliers and Price of Lithium, (methyldiphenylsilyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Lithium, (methyldiphenylsilyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:204.09465538
Heavy Atom Count:15
Complexity:142

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[Li+].C[Si-](C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Lithium, (methyldiphenylsilyl)-

There total 2 articles about Lithium, (methyldiphenylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 144-79-6
chloromethyldiphenylsilane

: 3839-30-3
methyldiphenylsilyllithium

Guidance literature:: With lithium; In tetrahydrofuran;
DOI:10.1016/0022-328X(86)80494-6

Reference yield:

: 3839-30-3
methyldiphenylsilyllithium

Guidance literature:: DOI:10.1002/hlca.19730560333

Reference yield: 99.0%

: 14377-63-0
1-(phenylglyoxylyl)piperidine

: (R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide

: 3839-30-3
methyldiphenylsilyllithium

: C₃₇H₄₃BrN₂O₃SSi

Guidance literature:: 1-(phenylglyoxylyl)piperidine; methyldiphenylsilyllithium; In tetrahydrofuran; at -70 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

(R)-N-(4-bromobenzylidene)-2-methylpropane-2-sulfinamide; In tetrahydrofuran; at -70 ℃; for 0.5h; diastereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.orglett.6b00006