2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime

Base Information

• Chemical Name: 2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime
• CAS No.: 38870-64-3
• Molecular Formula: C₅H₁₂N₂O₂
• Molecular Weight: 132.162
• DSSTox Substance ID: DTXSID40371423
• Mol file: 38870-64-3.mol

Synonyms:2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime;38870-64-3;DTXSID40371423;N-(3-oximino-2-methyl-2-butyl)hydroxylamine

Chemical Property of 2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime

Chemical Property:

• XLogP3: -0.1
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 132.089877630
• Heavy Atom Count: 9
• Complexity: 120

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=NO)C(C)(C)NO

Technology Process of 2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime

There total 1 articles about 2-Butanone, 3-(hydroxyamino)-3-methyl-, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

3-bromo-3,4,4-trimethyl-3,4-dihydrodiazete 1.2-dioxide (52533-27-4) → 3-hydroxy-3-methyl-butan-2-one oxime (7431-25-6) + 3-hydroxyamino-3-methyl-butan-2-one oxime (38870-64-3)

Guidance literature:

With potassium phosphate buffer; rac-cysteine; at 30 ℃; Rate constant; Mechanism; var. thiols, var. thiol conc. and pH;

DOI:10.1021/jm960737s

Reference yield: 71.0%

3-hydroxyamino-3-methyl-butan-2-one oxime (38870-64-3) + benzaldehyde (100-52-7) → 1-hydroxy-4,5,5-trimethyl-2-phenyl-3-imidazolin-3-oxide (155126-76-4)

Guidance literature:

In ethanol; for 10h; Heating;

DOI:10.1007/BF00698944

Reference yield: 45.0%

3-hydroxyamino-3-methyl-butan-2-one oxime (38870-64-3) + 2,2-dihydroxy-1-phenyl-ethanone (1075-06-5) → 2-benzoyl-4-hydroxy-4,5,5-trimethyl-2-imidazoline 3-oxide (107945-97-1)

Guidance literature:

In tetrahydrofuran; for 264h;

DOI:10.1007/BF01175059

upstream raw materials:

3-bromo-3,4,4-trimethyl-3,4-dihydrodiazete 1.2-dioxide

Downstream raw materials:

3-hydroxy-3-methyl-butan-2-one oxime

3-hydroxyamino-3-methyl-butan-2-one

2-benzoyl-4-hydroxy-4,5,5-trimethyl-2-imidazoline 3-oxide

1-hydroxy-4,5,5-trimethyl-2-phenyl-3-imidazolin-3-oxide