2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol

Base Information

Chemical Name:2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol
CAS No.:389076-87-3
Molecular Formula:C₃₃H₃₀O₃P₂
Molecular Weight:536.547
Hs Code.:
DSSTox Substance ID:DTXSID30579294
Nikkaji Number:J1.670.896H
Wikidata:Q82469781
Mol file:389076-87-3.mol

Synonyms:389076-87-3;2,6-bis(diphenylphosphorylmethyl)-4-methylphenol;2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol;DTXSID30579294

Suppliers and Price of 2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol

Chemical Property:

XLogP3:6.1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:8
Exact Mass:536.16701881
Heavy Atom Count:38
Complexity:708

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC(=C(C(=C1)CP(=O)(C2=CC=CC=C2)C3=CC=CC=C3)O)CP(=O)(C4=CC=CC=C4)C5=CC=CC=C5

Technology Process of 2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol

There total 1 articles about 2,6-Bis[(diphenylphosphoryl)methyl]-4-methylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 5862-32-8
2,6-bis(chloromethyl)-4-methylphenol

: 1706-90-7
methyl diphenylphosphinate

: 389076-87-3
4-methyl-2,6-bis(diphenylphosphinomethyl)phenol P,P'-dioxide

Guidance literature:: In xylene; Heating;
DOI:10.1007/s11172-006-0150-1

Reference yield: 66.0%

: 389076-87-3
4-methyl-2,6-bis(diphenylphosphinomethyl)phenol P,P'-dioxide

: neodymium(III) nitrate hexahydrate

: bis[2,6-bis(diphenylphosphorylmethyl)-4-methylphenol-O,O,O]tri(nitrato-O,O)neodymium(III) trihydrate

Guidance literature:: In chloroform; acetonitrile; under Ar atm.; stoich. amt. of metal salt in MeCN was slowly added dropwise to soln. of ligand in CHCl3 at about 25°C; soln. concd. (vac., about 5 Torr); ppt. filtered off; dried (vac., 5 Torr); elem. anal.;
DOI:10.1007/s11172-006-0150-1

Reference yield: 65.0%

: 389076-87-3
4-methyl-2,6-bis(diphenylphosphinomethyl)phenol P,P'-dioxide

: cerium(III) nitrate hexahydrate

: 75-05-8,26809-02-9
acetonitrile

: bis[2,6-bis(diphenylphosphorylmethyl)-4-methylphenol-O,O,O]tri(nitrato-O,O)cerium(III) trihydrate

: bis[2,6-bis(diphenylphosphorylmethyl)-4-formylphenolato-O,O](nitrato-O,O)cerium(III) hemihydrate diacetonitrile solvate

Guidance literature:: With air; In dichloromethane; acetonitrile; without protection from air; ligand dissolved in CH2Cl2; stoich. amt. ofmetal salt in MeCN was slowly added dropwise at about 25°C; anhyd. Et2O added; ppt. filtered off; washed (anhyd. Et2O); dried (vac.,1 Torr) at room temp.; filtrate was kept without protection from air fo r several hs; after storage overnight crystals were manually sepd.; purified in mineral oil;
DOI:10.1007/s11172-006-0150-1