tris(4-bromo-3-nitro-phenyl)arsane

Base Information

• Chemical Name: tris(4-bromo-3-nitro-phenyl)arsane
• CAS No.: 6306-92-9
• Molecular Formula: C₁₈H₉AsBr₃N₃O₆
• Molecular Weight: 677.92
• Hs Code.: 2931900090
• Mol file: 6306-92-9.mol

Synonyms:NSC 41653

Chemical Property of tris(4-bromo-3-nitro-phenyl)arsane

Chemical Property:

• Vapor Pressure: 1.22E-12mmHg at 25°C
• Boiling Point: 575.3°C at 760 mmHg
• Flash Point: 301.7°C
• PSA: 137.46000
• LogP: 5.78450

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris(4-bromo-3-nitro-phenyl)arsane

There total 6 articles about tris(4-bromo-3-nitro-phenyl)arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris-(4-bromo-3-nitro-phenyl)-arsine oxide (873413-35-5) → tris-(4-bromo-3-nitro-phenyl)-arsine (6306-92-9)

Guidance literature:

With hydrogen iodide; hypophosphoric acid; acetic acid;

DOI:10.1021/ja01847a061

Reference yield:

tris-(4-bromo-phenyl)-arsine oxide (4964-26-5) → tris-(4-bromo-3-nitro-phenyl)-arsine (6306-92-9)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfuric acid; nitric acid

2: hypophosphoric acid; hydrogen iodide; aqueous acetic acid

With sulfuric acid; hydrogen iodide; nitric acid; hypophosphoric acid; acetic acid;

DOI:10.1021/ja01847a061

Reference yield:

tris(4-bromophenyl)arsine (6306-93-0) → tris-(4-bromo-3-nitro-phenyl)-arsine (6306-92-9)

Guidance literature:

Multi-step reaction with 3 steps

1: acetone; potassium permanganate

2: sulfuric acid; nitric acid

3: hypophosphoric acid; hydrogen iodide; aqueous acetic acid

With potassium permanganate; sulfuric acid; hydrogen iodide; nitric acid; hypophosphoric acid; acetic acid; acetone;

DOI:10.1021/ja01847a061

upstream raw materials:

tris-(4-bromo-3-nitro-phenyl)-arsine oxide

tris(4-bromophenyl)arsine

tris-(4-bromo-phenyl)-arsine oxide

p-Bromophenyldibromoarsine