1,4-Diiodonorbornane

Base Information

• Chemical Name: 1,4-Diiodonorbornane
• CAS No.: 40950-21-8
• Molecular Formula: C7H10I2
• Molecular Weight: 347.965
• DSSTox Substance ID: DTXSID80193949
• Nikkaji Number: J270.961I
• Wikidata: Q83066678
• Mol file: 40950-21-8.mol

Synonyms:1,4-Diiodonorbornane;40950-21-8;1,4-diiodobicyclo[2.2.1]heptane;SCHEMBL24204498;DTXSID80193949

Chemical Property of 1,4-Diiodonorbornane

Chemical Property:

• Vapor Pressure: 0.00553mmHg at 25°C
• Boiling Point: 283.1°C at 760 mmHg
• Flash Point: 135.2°C
• Density: 2.35g/cm³
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 347.88720
• Heavy Atom Count: 9
• Complexity: 118

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1CC2(CCC1(C2)I)I

Technology Process of 1,4-Diiodonorbornane

There total 4 articles about 1,4-Diiodonorbornane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

4-iodobicyclo<2.2.1>heptane-1-carboxylic acid (123463-13-8) → 1,4-diiodobicyclo<2.2.1>heptane (40950-21-8)

Guidance literature:

With tert-Butyl hypoiodite; Irradiation;

DOI:10.1021/jo00287a014

Reference yield: 27.0%

1.4-Dichlornorbornan (2941-51-7) → 1,4-diiodobicyclo<2.2.1>heptane (40950-21-8)

Guidance literature:

With diiodomethane; bromine; aluminium; at 95 ℃; for 1h;

Reference yield:

1,4-Dichloronorbornan → 1,4-diiodobicyclo<2.2.1>heptane (40950-21-8)

Guidance literature:

With diiodomethane; bromine; aluminium;

DOI:10.1021/jo00878a011

upstream raw materials:

1.4-Dichlornorbornan

4-iodobicyclo<2.2.1>heptane-1-carboxylic acid

Downstream raw materials:

norbornene

1,1'-binorbornane

1-iodonorbornane

bis(1-norbornyl)mercury