METHALLYL ACRYLATE

Base Information

• Chemical Name: METHALLYL ACRYLATE
• CAS No.: 818-67-7
• Molecular Formula: C7H10O2
• Molecular Weight: 126.15
• Mol file: 818-67-7.mol

Synonyms:acrylic acid methallyl ester;Acrylsaeure-methallylester;METHALLYL ACRYLATE;2-methylprop-2-en-1-yl prop-2-enoate;Methallylacrylat;

Chemical Property of METHALLYL ACRYLATE

Chemical Property:

• Vapor Pressure: 4.44mmHg at 25°C
• Boiling Point: 147.4°C at 760 mmHg
• Flash Point: 46.3°C
• PSA: 26.30000
• Density: 0.917g/cm³
• LogP: 1.29170

Purity/Quality:

99% ^*data from raw suppliers

Methallylacrylate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHALLYL ACRYLATE

There total 9 articles about METHALLYL ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

acryloyl chloride (814-68-6,25189-84-8) + 3-hydroxy-2-methyl-1-propene (513-42-8) → acrylic acid methallyl ester (818-67-7)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201104073

Reference yield:

O-acetyl-lactic acid methallyl ester (500789-81-1) → acrylic acid methallyl ester (818-67-7)

Guidance literature:

With pyrexglass; at 550 ℃;

Reference yield:

lactic acid methallyl ester (69028-44-0) → acrylic acid methallyl ester (818-67-7)

Guidance literature:

Multi-step reaction with 2 steps

1: H₃PO₄ / 60 - 80 °C

2: pyrexglass / 550 °C

With phosphoric acid;

upstream raw materials:

O-acetyl-lactic acid methallyl ester

N-Phenyl-2-naphthylamine

aluminum isopropoxide

acrylic acid methyl ester

Downstream raw materials:

acrylic acid-(β,γ-epoxy-isobutyl ester)

2-{[hydroxy(phenyl)phosphinoyl]methyl}-4-methylpent-4-enoic acid

2-(2-Methyl-2-propenyl)-4-methylvaleric acid

Refernces

• 1、 Rogakos, Vassilis,Georgiadis, Dimitris,Dive, Vincent,Yiotakis, Athanaslos. "A modular rearrangement approach toward medicinally relevant phosphinic structures". supporting information; experimental part. p. 4696 - 4699. Retrieved 2009/12/08.