N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE

Base Information

• Chemical Name: N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE
• CAS No.: 3955-57-5
• Molecular Formula: C18H20N2O2
• Molecular Weight: 296.369
• Mol file: 3955-57-5.mol

Synonyms:N,N'-disalicylidene-butanediyldiamine;N,N'-disalicylidenetetramethylenediamine;

Chemical Property of N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE

Chemical Property:

• Melting Point: 90oC
• Boiling Point: 484.5oC at 760 mmHg
• Flash Point: 321.5oC
• PSA: 65.18000
• Density: 1.1g/cm3
• LogP: 3.41600
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

98%min ^*data from raw suppliers

N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

Useful:

Technology Process of N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE

There total 5 articles about N,N'-BIS(SALICYLIDENE)-1,4-BUTANEDIAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

salicylaldehyde (90-02-8) + 1,4-diaminobutane (110-60-1) → 2-bis{[(1E)-(2-hydroxyphenyl)methylene]amino}butane (3955-57-5)

Guidance literature:

In methanol; at 20 ℃; for 0.166667h;

DOI:10.1134/S1070428009040101

Reference yield: 96.8%

salicylaldehyde (90-02-8) + 1,4-diaminobutane (110-60-1) → N,N'-bis(salicylidene)-1,4-butanediamine (3955-57-5)

Guidance literature:

In N,N-dimethyl-formamide; at 20 ℃; for 6h;

Reference yield:

2-methyl-benzyl alcohol (89-95-2) + 1,4-diaminobutane (110-60-1) → 2-bis{[(1E)-(2-hydroxyphenyl)methylene]amino}butane (3955-57-5)

Guidance literature:

In ethanol; at 60 ℃; for 2h;

DOI:10.1002/(SICI)1521-3773(19990802)38:15<2237::AID-ANIE2237>3.0.CO;2-9

upstream raw materials:

salicylaldehyde

1,4-diaminobutane

2-methyl-benzyl alcohol

Downstream raw materials:

butylenediamine-N,N'-bis(2-hydroxyphenyl)acetic acid

C₄₂H₃₈N₂O₆P₂

Refernces

• 1、 Jia, Yufeng,Li, Hongfeng,Chen, Peng,Gao, Ting,Sun, Wenbin,Yan, Pengfei. "Magnetic and Optical Properties of Novel Lanthanide(III) Complexes Based on Schiff Base and β-Diketonate Ligands". . p. 527 - 533. Retrieved 2018.
• 2、 Hazari, Alokesh,Das, Lakshmi Kanta,Bauza, Antonio,Frontera, Antonio,Ghosh, Ashutosh. "The influence of H-bonding on the 'ambidentate' coordination behaviour of the thiocyanate ion to Cd(ii): A combined experimental and theoretical study". . p. 8007 - 8015. Retrieved 2014.
• 3、 Hazari, Alokesh,Ghosh, Ashutosh. "Trinuclear complexes of [CuL] (H2L = N,N′-bis(salicylidene)-1,4-butanediamine) with HgX2 (X- = N3- and NCO-): Facile crystallization with Z′ = 1 and Z′ = 0.5 for both complexes". . p. 403 - 410. Retrieved 2015.
• 4、 Bilge Ko?ak, Selen,Kaya, ?zgecan,Kili?, Zeynel,Coban, Burak,Yildiz, Ufuk,?o?ut, Bünyemin. "Syntheses, spectral and chiral properties and DNA interactions of multi-heterocyclic di- And trinuclear boron complexes". . p. 20966 - 20981. Retrieved 2020/12/31.