Decyltriphenylphosphonium bromide

Base Information

• Chemical Name: Decyltriphenylphosphonium bromide
• CAS No.: 32339-43-8
• Molecular Formula: C28H36BrP
• Molecular Weight: 483.472
• Hs Code.: 2931900090
• European Community (EC) Number: 250-996-8
• DSSTox Substance ID: DTXSID10954126
• Mol file: 32339-43-8.mol

Synonyms:Decyltriphenylphosphonium bromide;32339-43-8;(1-Decyl)triphenylphosphonium bromide;n-Decyl triphenylphosphonium bromide;Decyl-TPP bromide;32339-43-8 (bromide);EINECS 250-996-8;decyl(triphenyl)phosphanium bromide;decyl(triphenyl)phosphanium,bromide;Decyl-TPP;C28H36P.Br;SCHEMBL287291;Decyltriphenylphosphoniumbromide;C28-H36-P.Br;DTXSID10954126;GVPLMQGXUUHCSB-UHFFFAOYSA-M;decyl(triphenyl)phosphanium;bromide;decyl-triphenyl-phosphonium bromide;MFCD00051854;AKOS017345130;N-DECYLTRIPHENYLPHOSPHONIUMBROMIDE;CS-0044803;FT-0604510;J-018708

Chemical Property of Decyltriphenylphosphonium bromide

Chemical Property:

• Melting Point: 90 °C
• PSA: 13.59000
• LogP: 4.12520
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 482.17380
• Heavy Atom Count: 30
• Complexity: 353

Purity/Quality:

99%, ^*data from raw suppliers

Decyl-TPPBromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]

Technology Process of Decyltriphenylphosphonium bromide

There total 2 articles about Decyltriphenylphosphonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-bromo dodecane (112-29-8) + triphenylphosphine (603-35-0) → decyltriphenylphosphonium bromide (32339-43-8)

Guidance literature:

In toluene; Reflux;

DOI:10.1021/jf302872a

Reference yield:

→ decyltriphenylphosphonium bromide (32339-43-8)

Guidance literature:

Triphenylphosphin, entspr. Alkylhalogenid;

DOI:10.1016/0009-3084(71)90053-3

Reference yield: 95.0%

decyltriphenylphosphonium bromide (32339-43-8) + benzonitrile (100-47-0) → 1-phenylundecan-1-one (4433-30-1)

Guidance literature:

decyltriphenylphosphonium bromide; With n-butyllithium; lithium iodide; In tetrahydrofuran; hexane; for 0.333333h; cooling;

benzonitrile; In tetrahydrofuran; hexane; at 50 ℃; for 8h;

DOI:10.1021/jo050266u

upstream raw materials:

1-bromo dodecane

triphenylphosphine

Downstream raw materials:

decylidenetriphenylphosphorane

(2R,3R,4R,5E/Z)-1,3,4-tribenzyloxy-5-pentadecene-2-ol