2-Propanone, 1-(3-nitrophenyl)-

Base Information

• Chemical Name: 2-Propanone, 1-(3-nitrophenyl)-
• CAS No.: 39896-32-7
• Molecular Formula: C9H9NO3
• Molecular Weight: 179.175
• Mol file: 39896-32-7.mol

Synonyms:1-(m-nitro-phenyl)-propanone;1-(3-nitrophenyl)acetone;1-(m-nitro)-phenyl-2-propanone;m-nitrophenylacetone;3-nitrophenylacetone;1-(3-Nitro-phenyl)-propan-2-one;1-(3-nitrophenyl)-2-propanone;

Chemical Property of 2-Propanone, 1-(3-nitrophenyl)-

Chemical Property:

• Melting Point: 62 - 65 °C (methanol)
• PSA: 62.89000
• LogP: 2.24950

Purity/Quality:

98%min ^*data from raw suppliers

1-(3-Nitrophenyl)acetone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Propanone, 1-(3-nitrophenyl)-

There total 20 articles about 2-Propanone, 1-(3-nitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Isopropenyl acetate (108-22-5) + 3-nitro-aniline (99-09-2) → 1-(3-nitrophenyl)propan-2-one (39896-32-7)

Guidance literature:

3-nitro-aniline; With tetrafluoroboric acid; cis-nitrous acid;

Isopropenyl acetate; With copper(I) oxide; sodium acetate;

DOI:10.1080/00397910601163950

Reference yield: 75.0%

3-nitro-benzeneacetic acid (1877-73-2) + acetic acid (64-19-7,77671-22-8) → 1-(3-nitrophenyl)propan-2-one (39896-32-7)

Guidance literature:

3-nitro-benzeneacetic acid; acetic acid; In pyridine; at 20 ℃; for 4h;

With hydrogenchloride; In ethanol; water; for 1h; Reflux;

Reference yield: 71.0%

Okahara's reagent (105104-40-3) + tributyl(3-nitrophenyl)stannane (79048-31-0) → 1-(3-nitrophenyl)propan-2-one (39896-32-7)

Guidance literature:

bis-triphenylphosphine-palladium(II) chloride; In benzene; react. mixt. washed (aq. KF); extn.of org. layer (ether); dried over MgSO4; product isolated by distn. (reduced pressure); acetonylated by chromy. (silica gel);

DOI:10.1246/bcsj.62.3383

upstream raw materials:

(m-Nitrophenyl)allene

(Z)-1-(3-Nitro-phenyl)-propen-2-ol

(3-nitrophenyl)acetyl chloride

malonic acid dimethyl ester

Downstream raw materials:

2-methyl-2-(3-nitrobenzyl)-1,3-dioxolane

C₁₃H₁₅NO₅

N-(3-(1-(4-cyanophenyl)-3-methyl-6-oxo-1,6-dihydropyridazin-4-yl)phenyl)ethanesulfonamide

C₁₁H₁₁NO₅