Naphthalen-1-yl(diphenyl)phosphane sulfide

Base Information

Chemical Name:Naphthalen-1-yl(diphenyl)phosphane sulfide
CAS No.:3135-70-4
Molecular Formula:C22H17 P S
Molecular Weight:344.417
Hs Code.:
NSC Number:115016
DSSTox Substance ID:DTXSID50297266
Wikidata:Q82038280
Mol file:3135-70-4.mol

Synonyms:3135-70-4;naphthalen-1-yl(diphenyl)phosphane sulfide;NSC115016;DTXSID50297266;NSC-115016

Suppliers and Price of Naphthalen-1-yl(diphenyl)phosphane sulfide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Naphthalen-1-yl(diphenyl)phosphane sulfide

Chemical Property:

Vapor Pressure:4.54E-10mmHg at 25°C
Boiling Point:511.4°C at 760 mmHg
Flash Point:263.1°C
Density:1.24g/cm³
XLogP3:7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:344.07885871
Heavy Atom Count:24
Complexity:425

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(=S)(C2=CC=CC=C2)C3=CC=CC4=CC=CC=C43

Technology Process of Naphthalen-1-yl(diphenyl)phosphane sulfide

There total 3 articles about Naphthalen-1-yl(diphenyl)phosphane sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1162-90-9
1-naphthyl(diphenyl)phosphine

: 3135-70-4
diphenyl(1-naphthyl)phosphine sulfide

Guidance literature:: With sulfur; In toluene; at 20 ℃; for 48h;
DOI:10.1016/j.poly.2015.07.008

Reference yield: 97.0%

: 90-14-2
1-Iodonaphthalene

: 96620-51-8
(hydroxymethyl)diphenylphosphine sulfide

: 3135-70-4
diphenyl(1-naphthyl)phosphine sulfide

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 40 ℃; for 18h;
DOI:10.1021/ol303448j

Reference yield:

: 678187-53-6
(tert-butyldimethylsilyl)diphenylphosphine

: 3135-70-4
diphenyl(1-naphthyl)phosphine sulfide

Guidance literature:: Multi-step reaction with 2 steps

1.1: 2 h / 140 °C / Inert atmosphere

1.2: 6 h / 20 °C / Inert atmosphere

2.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 18 h / 40 °C

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene;
DOI:10.1021/ol303448j