(Naphthalen-1-yl)(diphenyl)phosphane

Base Information

• Chemical Name: (Naphthalen-1-yl)(diphenyl)phosphane
• CAS No.: 1162-90-9
• Molecular Formula: C22H17P
• Molecular Weight: 312.351
• DSSTox Substance ID: DTXSID50412396
• Nikkaji Number: J408.412H
• Wikidata: Q82219734
• Mol file: 1162-90-9.mol

Synonyms:(Naphthalen-1-yl)(diphenyl)phosphane;1162-90-9;1-naphthyldiphenylphosphine;naphthyl(diphenyl)phosphine;SCHEMBL132132;DTXSID50412396

Chemical Property of (Naphthalen-1-yl)(diphenyl)phosphane

Chemical Property:

• XLogP3: 5.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 312.106787540
• Heavy Atom Count: 23
• Complexity: 335

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC4=CC=CC=C43

Technology Process of (Naphthalen-1-yl)(diphenyl)phosphane

There total 28 articles about (Naphthalen-1-yl)(diphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-Bromonaphthalene (90-11-9) + (diphenylphosphino)(p-tolyl)methanone (40841-62-1) → 1-naphthyl(diphenyl)phosphine (1162-90-9)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; In toluene; at 100 ℃; for 12h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.1c00937

Reference yield: 95.0%

(diphenylphosphino)(p-tolyl)methanone (40841-62-1) + 1-naphthyl triflate (99747-74-7) → 1-naphthyl(diphenyl)phosphine (1162-90-9)

Guidance literature:

With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); caesium carbonate; In toluene; at 100 ℃; for 12h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.1c00937

Reference yield: 95.0%

H3B(PPh2(C10H7)) (220586-82-3) → 1-naphthyl(diphenyl)phosphine (1162-90-9)

Guidance literature:

In tetrahydrofuran; methanol; for 96h; Inert atmosphere; Molecular sieve; Reflux;

DOI:10.1016/j.jorganchem.2010.08.026

upstream raw materials:

1-Bromonaphthalene

chloro-diphenylphosphine

triphenylphosphine

1-Chloronaphthalene

Downstream raw materials:

(naphthalen-1-yl)diphenylphosphine oxide

trans-dichlorobis(diphenyl(1-naphthyl)phosphino)platinum(II)

[Pd(dibenzylideneacetone)(Ph₂P(1-naphthyl))2]

AuCl(P(1-naphthyl)Ph₂)