sodium 2-methyl-2-propanethiolate

Base Information

• Chemical Name: sodium 2-methyl-2-propanethiolate
• CAS No.: 4081-46-3
• Molecular Formula: C₄H₉AgS
• Molecular Weight: 197.05
• Hs Code.: 2930909090
• Mol file: 4081-46-3.mol

Synonyms:TetramethylheptanedionatosilverI;silver tert-butyl thiolate;silver 2,2,6,6-tetramethyl-3,5-heptanedionate;

Chemical Property of sodium 2-methyl-2-propanethiolate

Chemical Property:

• PSA: 0.00000
• LogP: 1.33180

Purity/Quality:

Sodium 2-methyl-2-propanethiolate technical grade, 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium 2-methyl-2-propanethiolate

There total 5 articles about sodium 2-methyl-2-propanethiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

silver nitrate + 2-methylpropan-2-thiol (75-66-1) → silver(I) 2-methyl-2-propanethiolate (4081-46-3)

Guidance literature:

In acetonitrile; to soln. of AgNO3 in MeCN under N2 was added ligand; collected, washed with MeOH, MeCN, dried under vac.; elem. anal.;

DOI:10.1021/ic010408c

Reference yield:

sodium tert-butyl thiolate (29364-29-2) + silver nitrate → silver(I) 2-methyl-2-propanethiolate (4081-46-3)

Guidance literature:

In methanol; mixing, according to: T. H. Joo, M. S. Kim, K. Kim, J. Raman. Spectrosc.18 (1987) 57; washing precipitates (methanol);

DOI:10.1016/S0022-2860(98)00895-3

Reference yield:

2-methylpropan-2-thiol (75-66-1) + silver(l) oxide (20667-12-3) → silver(I) 2-methyl-2-propanethiolate (4081-46-3)

Guidance literature:

With triethylamine;

DOI:10.1002/anie.201804059

upstream raw materials:

2-methylpropan-2-thiol

sodium tert-butyl thiolate

silver(l) oxide