cis-7-Tetradecene

Base Information

• Chemical Name: cis-7-Tetradecene
• CAS No.: 41446-60-0
• Molecular Formula: C₁₄H₂₈
• Molecular Weight: 196.376
• UNII: 0U2PR9165X
• DSSTox Substance ID: DTXSID501337508
• Nikkaji Number: J133.011J
• Wikidata: Q27237250
• Metabolomics Workbench ID: 4801
• Mol file: 41446-60-0.mol

Synonyms:(Z)-tetradec-7-ene;cis-7-tetradecene;7-Tetradecene, (Z)-;7-Tetradecene, cis-;7-Tetradecene, (7Z)-;(7Z)-7-Tetradecene;41446-60-0;7Z-Tetradecene;UNII-0U2PR9165X;(Z)-7-Tetradecene;0U2PR9165X;7-(Z)-Tetradecene;UBDIXSAEHLOROW-YPKPFQOOSA-N;DTXSID501337508;LMFA11000100;Q27237250

Chemical Property of cis-7-Tetradecene

Chemical Property:

• Boiling Point: 251.6±7.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.775±0.06 g/cm3(Predicted)
• LogP: 5.48340
• XLogP3: 6.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 196.219100893
• Heavy Atom Count: 14
• Complexity: 99.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCC=CCCCCCC
• Isomeric SMILES: CCCCCC/C=C\CCCCCC

Technology Process of cis-7-Tetradecene

There total 47 articles about cis-7-Tetradecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

7-tetradecyne (35216-11-6) → (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

With dmap; palladium(II) tetraphenylporphyrin; hydrogen; In pyridine; at 25 ℃; for 2h; under 760.051 Torr; stereoselective reaction;

DOI:10.1055/s-0033-1341240

Reference yield: 83.0%

oct-1-ene (111-66-0,25068-25-1) → (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0)

Guidance literature:

With C₂₉H₃₆N₃O₄Ru; In tetrahydrofuran; at 35 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ja210225e

Reference yield:

n-octyne (629-05-0) + dihexylboron chloride (18379-62-9) → (Z)-7-tetradecene (10374-74-0,41446-63-3,41446-60-0) + 1-Iodohexane (638-45-9)

Guidance literature:

With lithium aluminium tetrahydride; iodine; sodium methylate; multistep reaction; the effect of temperature on the formation of alkyl iodides;

DOI:10.1021/jo00237a003

upstream raw materials:

1-hexene

n-octyne

heptanal

triphenylheptylphosphonium bromide

Downstream raw materials:

(7S,8S)-8-Phenylselanyl-tetradecan-7-ol

heptanal

(E)-tetradec-7-ene epoxide

Refernces

• 1、 -. "SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS". Paragraph 0222; 0233. . Retrieved 2021/12/28.
• 2、 Ma?ecki, Pawe?,Gajda, Katarzyna,Gajda, Roman,Wo?niak, Krzysztof,Trzaskowski, Bartosz,Kajetanowicz, Anna,Grela, Karol. "Specialized ruthenium olefin metathesis catalysts bearing bulky unsymmetrical NHC Ligands: Computations, synthesis, and application". . p. 587 - 598. Retrieved 2019/01/08.